Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]
The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bon...
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| Format: | Article |
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International Union of Crystallography
2012
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| _version_ | 1825721995507007488 |
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| author | Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng |
| author_facet | Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng |
| author_sort | Zhang, Kou-Lin |
| collection | UM |
| description | The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-anti-prismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%]. |
| first_indexed | 2024-03-06T05:58:51Z |
| format | Article |
| id | um.eprints-23094 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:58:51Z |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-230942019-11-22T07:18:59Z http://eprints.um.edu.my/23094/ Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng Q Science (General) QD Chemistry The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C 8H 3O 7S)(C 12H 8N 2)(H 2O) 2]·2H 2O} n , bridges three water/phenanthroline-coordinated Dy III atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxylate group and is covalently bonded to a monodentate carboxylate group and to a monodentate sulfonate group in a distorted square-anti-prismatic geometry. The coordinating and the solvent water molecules are hydrogen bonded to the network. In the crystal, one solvent water molecule is disordered over two positions [major component = 59 (3)%]. International Union of Crystallography 2012 Article PeerReviewed Zhang, Kou-Lin and Lin, Jian-Guo and Ng, Seik Weng (2012) Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate]. Acta Crystallographica Section E: Structure Reports Online, 68 (3). m241-m241. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536812003613 <https://doi.org/10.1107/S1600536812003613>. https://doi.org/10.1107/S1600536812003613 doi:10.1107/S1600536812003613 |
| spellingShingle | Q Science (General) QD Chemistry Zhang, Kou-Lin Lin, Jian-Guo Ng, Seik Weng Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
| title | Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
| title_full | Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
| title_fullStr | Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
| title_full_unstemmed | Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
| title_short | Poly[[diaqua(1,10-phenanthroline-κ2N,N′)(μ3-4-sulfonatobenzene-1,2-dicarboxylato-κ4O1:O2,O2′:O4)dysprosium(III)] dihydrate] |
| title_sort | poly diaqua 1 10 phenanthroline κ2n n μ3 4 sulfonatobenzene 1 2 dicarboxylato κ4o1 o2 o2 o4 dysprosium iii dihydrate |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT zhangkoulin polydiaqua110phenanthrolinek2nnm34sulfonatobenzene12dicarboxylatok4o1o2o2o4dysprosiumiiidihydrate AT linjianguo polydiaqua110phenanthrolinek2nnm34sulfonatobenzene12dicarboxylatok4o1o2o2o4dysprosiumiiidihydrate AT ngseikweng polydiaqua110phenanthrolinek2nnm34sulfonatobenzene12dicarboxylatok4o1o2o2o4dysprosiumiiidihydrate |