Performance of melamine modified urea-formaldehyde microcapsules in a dental host material
Urea-formaldehyde (UF) microcapsules filled with dicyclopentadiene (DCPD) show potential for making self-healing dental restorative materials. To enhance the physical properties of the capsules, the urea was partially replaced with 0-5% melamine. The microcapsules were analyzed by different microsco...
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| Format: | Article |
| Language: | English |
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Wiley
2011
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| Online Access: | http://eprints.um.edu.my/2312/1/Performance_of_Melamine_Modified_Urea-Formaldehyde_Microcapsules_in_a_Dental_Host_Material.pdf |
| _version_ | 1825718660152426496 |
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| author | Then, S. Neon, G.S. Abu Kasim, Noor Hayaty |
| author_facet | Then, S. Neon, G.S. Abu Kasim, Noor Hayaty |
| author_sort | Then, S. |
| collection | UM |
| description | Urea-formaldehyde (UF) microcapsules filled with dicyclopentadiene (DCPD) show potential for making self-healing dental restorative materials. To enhance the physical properties of the capsules, the urea was partially replaced with 0-5% melamine. The microcapsules were analyzed by different microscopic techniques. DSC was used to examine the capsule shell, and the core content was confirmed by (1)H NMR spectroscopy. Capsules in the range of 50-300 mu m were then embedded in a dental composite matrix consisting of bisphenol-A-glycidyl dimethacrylate (Bis-GMA) and triethylene-glycol dimethacrylate (TEGDMA). Flexural strength, microhardness, and nanoindentation hardness measurements were performed on the light-cured specimens. Optical microscopy (OM) examination showed a random distribution of the microspheres throughout the host material. The incorporation of small amounts of the microcapsules did not affect the performance of the matrix material. Scanning electron microscopy (SEM) analysis revealed excellent bonding of the microcapsules to the host material which is a characteristic of utter importance for maintaining the very good mechanical properties of a dental composite with self-healing ability. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 122: 2557-2562, 2011 |
| first_indexed | 2024-03-06T05:07:47Z |
| format | Article |
| id | um.eprints-2312 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:07:47Z |
| publishDate | 2011 |
| publisher | Wiley |
| record_format | dspace |
| spelling | um.eprints-23122019-03-18T02:05:05Z http://eprints.um.edu.my/2312/ Performance of melamine modified urea-formaldehyde microcapsules in a dental host material Then, S. Neon, G.S. Abu Kasim, Noor Hayaty R Medicine RK Dentistry Urea-formaldehyde (UF) microcapsules filled with dicyclopentadiene (DCPD) show potential for making self-healing dental restorative materials. To enhance the physical properties of the capsules, the urea was partially replaced with 0-5% melamine. The microcapsules were analyzed by different microscopic techniques. DSC was used to examine the capsule shell, and the core content was confirmed by (1)H NMR spectroscopy. Capsules in the range of 50-300 mu m were then embedded in a dental composite matrix consisting of bisphenol-A-glycidyl dimethacrylate (Bis-GMA) and triethylene-glycol dimethacrylate (TEGDMA). Flexural strength, microhardness, and nanoindentation hardness measurements were performed on the light-cured specimens. Optical microscopy (OM) examination showed a random distribution of the microspheres throughout the host material. The incorporation of small amounts of the microcapsules did not affect the performance of the matrix material. Scanning electron microscopy (SEM) analysis revealed excellent bonding of the microcapsules to the host material which is a characteristic of utter importance for maintaining the very good mechanical properties of a dental composite with self-healing ability. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 122: 2557-2562, 2011 Wiley 2011-11 Article PeerReviewed application/pdf en http://eprints.um.edu.my/2312/1/Performance_of_Melamine_Modified_Urea-Formaldehyde_Microcapsules_in_a_Dental_Host_Material.pdf Then, S. and Neon, G.S. and Abu Kasim, Noor Hayaty (2011) Performance of melamine modified urea-formaldehyde microcapsules in a dental host material. Journal of Applied Polymer Science, 122 (4). pp. 2557-2562. ISSN 0021-8995, DOI https://doi.org/10.1002/app.34361 <https://doi.org/10.1002/app.34361>. http://WOS:000294772400046 10.1002/app.34361 |
| spellingShingle | R Medicine RK Dentistry Then, S. Neon, G.S. Abu Kasim, Noor Hayaty Performance of melamine modified urea-formaldehyde microcapsules in a dental host material |
| title | Performance of melamine modified urea-formaldehyde microcapsules in a dental host material |
| title_full | Performance of melamine modified urea-formaldehyde microcapsules in a dental host material |
| title_fullStr | Performance of melamine modified urea-formaldehyde microcapsules in a dental host material |
| title_full_unstemmed | Performance of melamine modified urea-formaldehyde microcapsules in a dental host material |
| title_short | Performance of melamine modified urea-formaldehyde microcapsules in a dental host material |
| title_sort | performance of melamine modified urea formaldehyde microcapsules in a dental host material |
| topic | R Medicine RK Dentistry |
| url | http://eprints.um.edu.my/2312/1/Performance_of_Melamine_Modified_Urea-Formaldehyde_Microcapsules_in_a_Dental_Host_Material.pdf |
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