Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri]
Removal of phthalates in environmental compartments become crucial in recent years due to the growing global concern about the health effects of phthalates. In this study, a greener method based on cloud point extraction procedure was developed for the removal of selected phthalates in environmental...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Published: |
Malaysian Analytical Sciences Society
2019
|
| Subjects: |
| _version_ | 1825722125686669312 |
|---|---|
| author | Ooi, Pei Wan Ramachandran, Muggundha Raoov Yahaya, Noorfatimah Nik Mohamed Kamal, Nik Nur Syazni Gopal, Kasturi Husin, Nor Aniisah Zain, Nur Nadhirah Mohamad |
| author_facet | Ooi, Pei Wan Ramachandran, Muggundha Raoov Yahaya, Noorfatimah Nik Mohamed Kamal, Nik Nur Syazni Gopal, Kasturi Husin, Nor Aniisah Zain, Nur Nadhirah Mohamad |
| author_sort | Ooi, Pei Wan |
| collection | UM |
| description | Removal of phthalates in environmental compartments become crucial in recent years due to the growing global concern about the health effects of phthalates. In this study, a greener method based on cloud point extraction procedure was developed for the removal of selected phthalates in environmental samples using non-ionic silicone surfactant (DC193C). The parameters affecting the extraction efficiency, such as the surfactant concentration, salt types, salt concentration, temperature and incubation time were evaluated and optimized. Good linearity with correlation coefficients (R2) in the range of 0.9963 – 0.9988 for all calibration curves was obtained. The proposed method was applied in removing the diethhylhexyl phthalate and dibutyl phthalate in river water samples under optimized conditions with satisfactory recoveries in the range of 82 – 98%. © 2019, Malaysian Society of Analytical Sciences. All rights reserved. |
| first_indexed | 2024-03-06T06:00:53Z |
| format | Article |
| id | um.eprints-23787 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T06:00:53Z |
| publishDate | 2019 |
| publisher | Malaysian Analytical Sciences Society |
| record_format | dspace |
| spelling | um.eprints-237872020-02-14T02:16:24Z http://eprints.um.edu.my/23787/ Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri] Ooi, Pei Wan Ramachandran, Muggundha Raoov Yahaya, Noorfatimah Nik Mohamed Kamal, Nik Nur Syazni Gopal, Kasturi Husin, Nor Aniisah Zain, Nur Nadhirah Mohamad Q Science (General) QD Chemistry Removal of phthalates in environmental compartments become crucial in recent years due to the growing global concern about the health effects of phthalates. In this study, a greener method based on cloud point extraction procedure was developed for the removal of selected phthalates in environmental samples using non-ionic silicone surfactant (DC193C). The parameters affecting the extraction efficiency, such as the surfactant concentration, salt types, salt concentration, temperature and incubation time were evaluated and optimized. Good linearity with correlation coefficients (R2) in the range of 0.9963 – 0.9988 for all calibration curves was obtained. The proposed method was applied in removing the diethhylhexyl phthalate and dibutyl phthalate in river water samples under optimized conditions with satisfactory recoveries in the range of 82 – 98%. © 2019, Malaysian Society of Analytical Sciences. All rights reserved. Malaysian Analytical Sciences Society 2019 Article PeerReviewed Ooi, Pei Wan and Ramachandran, Muggundha Raoov and Yahaya, Noorfatimah and Nik Mohamed Kamal, Nik Nur Syazni and Gopal, Kasturi and Husin, Nor Aniisah and Zain, Nur Nadhirah Mohamad (2019) Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri]. Malaysian Journal of Analytical Sciences, 23 (5). pp. 839-848. ISSN 1394-2506, http://www.ukm.my/mjas/v23_n5/html/23_5_9.html |
| spellingShingle | Q Science (General) QD Chemistry Ooi, Pei Wan Ramachandran, Muggundha Raoov Yahaya, Noorfatimah Nik Mohamed Kamal, Nik Nur Syazni Gopal, Kasturi Husin, Nor Aniisah Zain, Nur Nadhirah Mohamad Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri] |
| title | Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri] |
| title_full | Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri] |
| title_fullStr | Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri] |
| title_full_unstemmed | Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri] |
| title_short | Removal of phthalates in aqueos samples using non-ionic silicone surfactant mediated cloud point extraction via spectrophotometry [Penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri] |
| title_sort | removal of phthalates in aqueos samples using non ionic silicone surfactant mediated cloud point extraction via spectrophotometry penyingkiran ftalat dalam sampel akues menggunakan teknik pengekstrakan titik awan surfaktan silikon tidak berionik dengan spektrofotometri |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT ooipeiwan removalofphthalatesinaqueossamplesusingnonionicsiliconesurfactantmediatedcloudpointextractionviaspectrophotometrypenyingkiranftalatdalamsampelakuesmenggunakanteknikpengekstrakantitikawansurfaktansilikontidakberionikdenganspektrofotometri AT ramachandranmuggundharaoov removalofphthalatesinaqueossamplesusingnonionicsiliconesurfactantmediatedcloudpointextractionviaspectrophotometrypenyingkiranftalatdalamsampelakuesmenggunakanteknikpengekstrakantitikawansurfaktansilikontidakberionikdenganspektrofotometri AT yahayanoorfatimah removalofphthalatesinaqueossamplesusingnonionicsiliconesurfactantmediatedcloudpointextractionviaspectrophotometrypenyingkiranftalatdalamsampelakuesmenggunakanteknikpengekstrakantitikawansurfaktansilikontidakberionikdenganspektrofotometri AT nikmohamedkamalniknursyazni removalofphthalatesinaqueossamplesusingnonionicsiliconesurfactantmediatedcloudpointextractionviaspectrophotometrypenyingkiranftalatdalamsampelakuesmenggunakanteknikpengekstrakantitikawansurfaktansilikontidakberionikdenganspektrofotometri AT gopalkasturi removalofphthalatesinaqueossamplesusingnonionicsiliconesurfactantmediatedcloudpointextractionviaspectrophotometrypenyingkiranftalatdalamsampelakuesmenggunakanteknikpengekstrakantitikawansurfaktansilikontidakberionikdenganspektrofotometri AT husinnoraniisah removalofphthalatesinaqueossamplesusingnonionicsiliconesurfactantmediatedcloudpointextractionviaspectrophotometrypenyingkiranftalatdalamsampelakuesmenggunakanteknikpengekstrakantitikawansurfaktansilikontidakberionikdenganspektrofotometri AT zainnurnadhirahmohamad removalofphthalatesinaqueossamplesusingnonionicsiliconesurfactantmediatedcloudpointextractionviaspectrophotometrypenyingkiranftalatdalamsampelakuesmenggunakanteknikpengekstrakantitikawansurfaktansilikontidakberionikdenganspektrofotometri |