Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch

In this study, a simple, green and eco-friendly method was used for the synthesis of silver nanoparticles (Ag-NPs) in alkaline treated Tapioca starch. The XRD results indicated that Ag-NPs were produced after stirring for several hours at 80 °C. TEM image showed the Ag-NPs were in spherical shape wi...

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Main Authors: Kalantari, Katayoon, Afifi, Amalina Muhammad, Bayat, Saadi, Shameli, Kamyar, Yousefi, Samira, Mokhtar, Norrashidah, Kalantari, Alireza
Format: Article
Published: Elsevier 2019
Subjects:
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author Kalantari, Katayoon
Afifi, Amalina Muhammad
Bayat, Saadi
Shameli, Kamyar
Yousefi, Samira
Mokhtar, Norrashidah
Kalantari, Alireza
author_facet Kalantari, Katayoon
Afifi, Amalina Muhammad
Bayat, Saadi
Shameli, Kamyar
Yousefi, Samira
Mokhtar, Norrashidah
Kalantari, Alireza
author_sort Kalantari, Katayoon
collection UM
description In this study, a simple, green and eco-friendly method was used for the synthesis of silver nanoparticles (Ag-NPs) in alkaline treated Tapioca starch. The XRD results indicated that Ag-NPs were produced after stirring for several hours at 80 °C. TEM image showed the Ag-NPs were in spherical shape with average size of 11 nm. The UV–vis results revealed clearly the formation of Ag-NPs in the range from 410 to 420 nm. Moreover, the prepared nanoparticles showed good catalytic activity in the reduction of 4-nitrophenol (4-NP). The results confirmed the catalytic activity of them in the short induction period, and the completion reaction continued within 15 min. The finding revealed also significant shift in the DPPH radical scavenging ability for studied samples. The recorded scavenging ability for the lowest concentration of the synthesized Ag-NP (50 μg/ml) was 17.29 ± 0.06 and this scavenging ability was increased to 78.60 ± 0.05, when concentration was increased to 250 μg/ml. Silver nanoparticles have many catalytic and antioxidant activities in environmental and biomedical fields. © 2016 The Authors
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spelling um.eprints-241572020-04-06T15:44:03Z http://eprints.um.edu.my/24157/ Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch Kalantari, Katayoon Afifi, Amalina Muhammad Bayat, Saadi Shameli, Kamyar Yousefi, Samira Mokhtar, Norrashidah Kalantari, Alireza QD Chemistry TJ Mechanical engineering and machinery In this study, a simple, green and eco-friendly method was used for the synthesis of silver nanoparticles (Ag-NPs) in alkaline treated Tapioca starch. The XRD results indicated that Ag-NPs were produced after stirring for several hours at 80 °C. TEM image showed the Ag-NPs were in spherical shape with average size of 11 nm. The UV–vis results revealed clearly the formation of Ag-NPs in the range from 410 to 420 nm. Moreover, the prepared nanoparticles showed good catalytic activity in the reduction of 4-nitrophenol (4-NP). The results confirmed the catalytic activity of them in the short induction period, and the completion reaction continued within 15 min. The finding revealed also significant shift in the DPPH radical scavenging ability for studied samples. The recorded scavenging ability for the lowest concentration of the synthesized Ag-NP (50 μg/ml) was 17.29 ± 0.06 and this scavenging ability was increased to 78.60 ± 0.05, when concentration was increased to 250 μg/ml. Silver nanoparticles have many catalytic and antioxidant activities in environmental and biomedical fields. © 2016 The Authors Elsevier 2019 Article PeerReviewed Kalantari, Katayoon and Afifi, Amalina Muhammad and Bayat, Saadi and Shameli, Kamyar and Yousefi, Samira and Mokhtar, Norrashidah and Kalantari, Alireza (2019) Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch. Arabian Journal of Chemistry, 12 (8). pp. 5246-5252. ISSN 1878-5352, DOI https://doi.org/10.1016/j.arabjc.2016.12.018 <https://doi.org/10.1016/j.arabjc.2016.12.018>. https://doi.org/10.1016/j.arabjc.2016.12.018 doi:10.1016/j.arabjc.2016.12.018
spellingShingle QD Chemistry
TJ Mechanical engineering and machinery
Kalantari, Katayoon
Afifi, Amalina Muhammad
Bayat, Saadi
Shameli, Kamyar
Yousefi, Samira
Mokhtar, Norrashidah
Kalantari, Alireza
Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch
title Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch
title_full Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch
title_fullStr Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch
title_full_unstemmed Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch
title_short Heterogeneous catalysis in 4-nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in Tapioca starch
title_sort heterogeneous catalysis in 4 nitrophenol degradation and antioxidant activities of silver nanoparticles embedded in tapioca starch
topic QD Chemistry
TJ Mechanical engineering and machinery
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