The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects
Product and rate studies of the thermal decomposition of t-butyl peroxide in a series of alkyl benzyl ethers PhCH2·OR (R = Me, Et, Pri, But, or Ph) show little induced decomposition of the peroxide by the ether radical PhĊHOR, whereas in the case of the chloro-substituted ethers ArCH2·OR (Ar = 4-ClC...
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| Format: | Article |
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Royal Society of Chemistry
1971
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| author | Goh, S.H. Huang, R.L. Ong, S.H. Sieh, I. |
| author_facet | Goh, S.H. Huang, R.L. Ong, S.H. Sieh, I. |
| author_sort | Goh, S.H. |
| collection | UM |
| description | Product and rate studies of the thermal decomposition of t-butyl peroxide in a series of alkyl benzyl ethers PhCH2·OR (R = Me, Et, Pri, But, or Ph) show little induced decomposition of the peroxide by the ether radical PhĊHOR, whereas in the case of the chloro-substituted ethers ArCH2·OR (Ar = 4-ClC 6H4 or 3,4-Cl2C6H3, R = Me, Et, Pri, But, or Ph) induced decomposition does occur to widely varying degrees, showing marked steric influence by the group R. |
| first_indexed | 2024-03-06T06:02:43Z |
| format | Article |
| id | um.eprints-24416 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T06:02:43Z |
| publishDate | 1971 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | um.eprints-244162021-03-24T05:34:00Z http://eprints.um.edu.my/24416/ The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects Goh, S.H. Huang, R.L. Ong, S.H. Sieh, I. QD Chemistry Product and rate studies of the thermal decomposition of t-butyl peroxide in a series of alkyl benzyl ethers PhCH2·OR (R = Me, Et, Pri, But, or Ph) show little induced decomposition of the peroxide by the ether radical PhĊHOR, whereas in the case of the chloro-substituted ethers ArCH2·OR (Ar = 4-ClC 6H4 or 3,4-Cl2C6H3, R = Me, Et, Pri, But, or Ph) induced decomposition does occur to widely varying degrees, showing marked steric influence by the group R. Royal Society of Chemistry 1971 Article PeerReviewed Goh, S.H. and Huang, R.L. and Ong, S.H. and Sieh, I. (1971) The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects. Journal of the Chemical Society C: Organic. pp. 2282-2286. ISSN 0022-4952, DOI https://doi.org/10.1039/J39710002282 <https://doi.org/10.1039/J39710002282>. https://doi.org/10.1039/J39710002282 doi:10.1039/J39710002282 |
| spellingShingle | QD Chemistry Goh, S.H. Huang, R.L. Ong, S.H. Sieh, I. The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects |
| title | The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects |
| title_full | The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects |
| title_fullStr | The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects |
| title_full_unstemmed | The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects |
| title_short | The induced decomposition of t-butyl peroxide in solution. Part III. Decomposition of t-butyl peroxide in alkyl benzyl ethers; steric effects |
| title_sort | induced decomposition of t butyl peroxide in solution part iii decomposition of t butyl peroxide in alkyl benzyl ethers steric effects |
| topic | QD Chemistry |
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