Hydrolysis products of dibutyltin dichlorides
The hydrolysis of di-s-butyltin dichloride yields similar products to those found for the di-n-butyl compound whereas the hydrolysis behaviour of di-t-butyltin dichloride is markedly different. Distannoxanes are not found in the latter case but instead di-t-butyltin hydroxide chloride is obtained. U...
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| Format: | Article |
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Royal Society of Chemistry
1971
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| _version_ | 1796962023192395776 |
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| author | Chua, C.K. Murray, J.D. |
| author_facet | Chua, C.K. Murray, J.D. |
| author_sort | Chua, C.K. |
| collection | UM |
| description | The hydrolysis of di-s-butyltin dichloride yields similar products to those found for the di-n-butyl compound whereas the hydrolysis behaviour of di-t-butyltin dichloride is markedly different. Distannoxanes are not found in the latter case but instead di-t-butyltin hydroxide chloride is obtained. Under strongly basic conditions di-t-butyltin oxide is formed which has unusual structural properties and can easily be converted into a 'dihydroxide.' Comparative i.r. data derived from analogous systems are presented. |
| first_indexed | 2024-03-06T06:02:51Z |
| format | Article |
| id | um.eprints-24468 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T06:02:51Z |
| publishDate | 1971 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | um.eprints-244682021-03-24T04:28:15Z http://eprints.um.edu.my/24468/ Hydrolysis products of dibutyltin dichlorides Chua, C.K. Murray, J.D. Q Science (General) QD Chemistry The hydrolysis of di-s-butyltin dichloride yields similar products to those found for the di-n-butyl compound whereas the hydrolysis behaviour of di-t-butyltin dichloride is markedly different. Distannoxanes are not found in the latter case but instead di-t-butyltin hydroxide chloride is obtained. Under strongly basic conditions di-t-butyltin oxide is formed which has unusual structural properties and can easily be converted into a 'dihydroxide.' Comparative i.r. data derived from analogous systems are presented. Royal Society of Chemistry 1971 Article PeerReviewed Chua, C.K. and Murray, J.D. (1971) Hydrolysis products of dibutyltin dichlorides. Journal of the Chemical Society A: Inorganic, Physical, and Theoretical Chemistry. pp. 360-367. ISSN 0022-4944, DOI https://doi.org/10.1039/J19710000360 <https://doi.org/10.1039/J19710000360>. https://doi.org/10.1039/J19710000360 doi:10.1039/J19710000360 |
| spellingShingle | Q Science (General) QD Chemistry Chua, C.K. Murray, J.D. Hydrolysis products of dibutyltin dichlorides |
| title | Hydrolysis products of dibutyltin dichlorides |
| title_full | Hydrolysis products of dibutyltin dichlorides |
| title_fullStr | Hydrolysis products of dibutyltin dichlorides |
| title_full_unstemmed | Hydrolysis products of dibutyltin dichlorides |
| title_short | Hydrolysis products of dibutyltin dichlorides |
| title_sort | hydrolysis products of dibutyltin dichlorides |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT chuack hydrolysisproductsofdibutyltindichlorides AT murrayjd hydrolysisproductsofdibutyltindichlorides |