Phenylation of azobenzene
The substituent effect of the phenylazo-group in homolytic phenylation has been measured with azobenzene as substrate and nitrobenzene as reference compound. Even after allowance for the large number of sites of substitution the phenylazo-group was shown to equal the nitro-group in its activating po...
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Format: | Article |
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Royal Society of Chemistry
1970
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Summary: | The substituent effect of the phenylazo-group in homolytic phenylation has been measured with azobenzene as substrate and nitrobenzene as reference compound. Even after allowance for the large number of sites of substitution the phenylazo-group was shown to equal the nitro-group in its activating power. Isomer ratios and partial rate factors have been determined and are discussed. © Royal Society of Chemistry. |
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