Phenylation of azobenzene
The substituent effect of the phenylazo-group in homolytic phenylation has been measured with azobenzene as substrate and nitrobenzene as reference compound. Even after allowance for the large number of sites of substitution the phenylazo-group was shown to equal the nitro-group in its activating po...
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Royal Society of Chemistry
1970
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author | Miller, Joseph Paul, D.B. Wong, L.Y. Kelso, A.G. |
author_facet | Miller, Joseph Paul, D.B. Wong, L.Y. Kelso, A.G. |
author_sort | Miller, Joseph |
collection | UM |
description | The substituent effect of the phenylazo-group in homolytic phenylation has been measured with azobenzene as substrate and nitrobenzene as reference compound. Even after allowance for the large number of sites of substitution the phenylazo-group was shown to equal the nitro-group in its activating power. Isomer ratios and partial rate factors have been determined and are discussed. © Royal Society of Chemistry. |
first_indexed | 2024-03-06T06:03:03Z |
format | Article |
id | um.eprints-24536 |
institution | Universiti Malaya |
last_indexed | 2024-03-06T06:03:03Z |
publishDate | 1970 |
publisher | Royal Society of Chemistry |
record_format | dspace |
spelling | um.eprints-245362021-03-22T04:42:59Z http://eprints.um.edu.my/24536/ Phenylation of azobenzene Miller, Joseph Paul, D.B. Wong, L.Y. Kelso, A.G. Q Science (General) QD Chemistry The substituent effect of the phenylazo-group in homolytic phenylation has been measured with azobenzene as substrate and nitrobenzene as reference compound. Even after allowance for the large number of sites of substitution the phenylazo-group was shown to equal the nitro-group in its activating power. Isomer ratios and partial rate factors have been determined and are discussed. © Royal Society of Chemistry. Royal Society of Chemistry 1970 Article PeerReviewed Miller, Joseph and Paul, D.B. and Wong, L.Y. and Kelso, A.G. (1970) Phenylation of azobenzene. Journal of the Chemical Society B: Physical Organic. pp. 62-65. ISSN 0045-6470, DOI https://doi.org/10.1039/J29700000062 <https://doi.org/10.1039/J29700000062>. https://doi.org/10.1039/J29700000062 doi:10.1039/J29700000062 |
spellingShingle | Q Science (General) QD Chemistry Miller, Joseph Paul, D.B. Wong, L.Y. Kelso, A.G. Phenylation of azobenzene |
title | Phenylation of azobenzene |
title_full | Phenylation of azobenzene |
title_fullStr | Phenylation of azobenzene |
title_full_unstemmed | Phenylation of azobenzene |
title_short | Phenylation of azobenzene |
title_sort | phenylation of azobenzene |
topic | Q Science (General) QD Chemistry |
work_keys_str_mv | AT millerjoseph phenylationofazobenzene AT pauldb phenylationofazobenzene AT wongly phenylationofazobenzene AT kelsoag phenylationofazobenzene |