Phenylation of azobenzene

The substituent effect of the phenylazo-group in homolytic phenylation has been measured with azobenzene as substrate and nitrobenzene as reference compound. Even after allowance for the large number of sites of substitution the phenylazo-group was shown to equal the nitro-group in its activating po...

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Main Authors: Miller, Joseph, Paul, D.B., Wong, L.Y., Kelso, A.G.
Format: Article
Published: Royal Society of Chemistry 1970
Subjects:
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author Miller, Joseph
Paul, D.B.
Wong, L.Y.
Kelso, A.G.
author_facet Miller, Joseph
Paul, D.B.
Wong, L.Y.
Kelso, A.G.
author_sort Miller, Joseph
collection UM
description The substituent effect of the phenylazo-group in homolytic phenylation has been measured with azobenzene as substrate and nitrobenzene as reference compound. Even after allowance for the large number of sites of substitution the phenylazo-group was shown to equal the nitro-group in its activating power. Isomer ratios and partial rate factors have been determined and are discussed. © Royal Society of Chemistry.
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spelling um.eprints-245362021-03-22T04:42:59Z http://eprints.um.edu.my/24536/ Phenylation of azobenzene Miller, Joseph Paul, D.B. Wong, L.Y. Kelso, A.G. Q Science (General) QD Chemistry The substituent effect of the phenylazo-group in homolytic phenylation has been measured with azobenzene as substrate and nitrobenzene as reference compound. Even after allowance for the large number of sites of substitution the phenylazo-group was shown to equal the nitro-group in its activating power. Isomer ratios and partial rate factors have been determined and are discussed. © Royal Society of Chemistry. Royal Society of Chemistry 1970 Article PeerReviewed Miller, Joseph and Paul, D.B. and Wong, L.Y. and Kelso, A.G. (1970) Phenylation of azobenzene. Journal of the Chemical Society B: Physical Organic. pp. 62-65. ISSN 0045-6470, DOI https://doi.org/10.1039/J29700000062 <https://doi.org/10.1039/J29700000062>. https://doi.org/10.1039/J29700000062 doi:10.1039/J29700000062
spellingShingle Q Science (General)
QD Chemistry
Miller, Joseph
Paul, D.B.
Wong, L.Y.
Kelso, A.G.
Phenylation of azobenzene
title Phenylation of azobenzene
title_full Phenylation of azobenzene
title_fullStr Phenylation of azobenzene
title_full_unstemmed Phenylation of azobenzene
title_short Phenylation of azobenzene
title_sort phenylation of azobenzene
topic Q Science (General)
QD Chemistry
work_keys_str_mv AT millerjoseph phenylationofazobenzene
AT pauldb phenylationofazobenzene
AT wongly phenylationofazobenzene
AT kelsoag phenylationofazobenzene