Synthesis and properties of alkyl hydrazonates
The solvolysis of hydrazonyl bromides in alcohols (methanol, ethanol, or propanol) gave the equivalent alkyl hydrazonates. The best results were obtained by use of alcohols buffered with sodium acetate. The alkyl hydrazonates were found to be more stable than the analogous alkyl imidates and strong...
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| Format: | Article |
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Royal Society of Chemistry
1970
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| author | Aylward, J.B. Scott, F.L. |
| author_facet | Aylward, J.B. Scott, F.L. |
| author_sort | Aylward, J.B. |
| collection | UM |
| description | The solvolysis of hydrazonyl bromides in alcohols (methanol, ethanol, or propanol) gave the equivalent alkyl hydrazonates. The best results were obtained by use of alcohols buffered with sodium acetate. The alkyl hydrazonates were found to be more stable than the analogous alkyl imidates and strong acid was required to cleave them. An attempt to effect a Chapman rearrangement of these materials was unsuccessful. |
| first_indexed | 2024-03-06T06:03:05Z |
| format | Article |
| id | um.eprints-24547 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T06:03:05Z |
| publishDate | 1970 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | um.eprints-245472021-03-22T04:15:44Z http://eprints.um.edu.my/24547/ Synthesis and properties of alkyl hydrazonates Aylward, J.B. Scott, F.L. Q Science (General) QD Chemistry The solvolysis of hydrazonyl bromides in alcohols (methanol, ethanol, or propanol) gave the equivalent alkyl hydrazonates. The best results were obtained by use of alcohols buffered with sodium acetate. The alkyl hydrazonates were found to be more stable than the analogous alkyl imidates and strong acid was required to cleave them. An attempt to effect a Chapman rearrangement of these materials was unsuccessful. Royal Society of Chemistry 1970 Article PeerReviewed Aylward, J.B. and Scott, F.L. (1970) Synthesis and properties of alkyl hydrazonates. Journal of the Chemical Society C: Organic, 7. pp. 968-970. ISSN 0022-4952, DOI https://doi.org/10.1039/J39700000968 <https://doi.org/10.1039/J39700000968>. https://doi.org/10.1039/J39700000968 doi:10.1039/J39700000968 |
| spellingShingle | Q Science (General) QD Chemistry Aylward, J.B. Scott, F.L. Synthesis and properties of alkyl hydrazonates |
| title | Synthesis and properties of alkyl hydrazonates |
| title_full | Synthesis and properties of alkyl hydrazonates |
| title_fullStr | Synthesis and properties of alkyl hydrazonates |
| title_full_unstemmed | Synthesis and properties of alkyl hydrazonates |
| title_short | Synthesis and properties of alkyl hydrazonates |
| title_sort | synthesis and properties of alkyl hydrazonates |
| topic | Q Science (General) QD Chemistry |
| work_keys_str_mv | AT aylwardjb synthesisandpropertiesofalkylhydrazonates AT scottfl synthesisandpropertiesofalkylhydrazonates |