Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide

1-Methyl-3-propylimidazolium iodide (MPII) ionic liquid incorporated gel polymer electrolyte (GPE) has successfully enhanced the efficiency of a dye-sensitized solar cell (DSSC). A series of gel polymer electrolytes containing different amounts of MPII were prepared and characterized. A maximum ioni...

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Main Authors: Tan, Chee Yu, Saidi, Norshahirah Mohamad, Farhana, N.K., Omar, Fatin Saiha, Algaradah, Mohammed M., Bashir, Shahid, Ramesh, Subramaniam, Ramesh, Kasi
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Published: Springer Verlag (Germany) 2020
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author Tan, Chee Yu
Saidi, Norshahirah Mohamad
Farhana, N.K.
Omar, Fatin Saiha
Algaradah, Mohammed M.
Bashir, Shahid
Ramesh, Subramaniam
Ramesh, Kasi
author_facet Tan, Chee Yu
Saidi, Norshahirah Mohamad
Farhana, N.K.
Omar, Fatin Saiha
Algaradah, Mohammed M.
Bashir, Shahid
Ramesh, Subramaniam
Ramesh, Kasi
author_sort Tan, Chee Yu
collection UM
description 1-Methyl-3-propylimidazolium iodide (MPII) ionic liquid incorporated gel polymer electrolyte (GPE) has successfully enhanced the efficiency of a dye-sensitized solar cell (DSSC). A series of gel polymer electrolytes containing different amounts of MPII were prepared and characterized. A maximum ionic conductivity of 3.99 mS cm−1 was obtained in a GPE containing 10 wt% MPII, which was accompanied by the lowest activation energy. The results from dielectric studies showed typical behaviour for both ɛ’ and ɛ” in which their values decreased with increasing frequency but increased proportionately with temperature. From the results of FESEM, the morphologies of the GPE became slightly rougher after the addition of MPII. Dye-sensitized solar cells were fabricated and characterized using electrochemical impedance spectroscopy (EIS) and photovoltaic studies. DSSC with the best performance (4.35% of efficiency, 9.97 mA cm−2 of JSC, 0.67 V of VOC, and 65.39% of fill factor) was assembled using the GPE with 10 wt% of MPII. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature.
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spelling um.eprints-248362020-06-16T01:32:03Z http://eprints.um.edu.my/24836/ Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide Tan, Chee Yu Saidi, Norshahirah Mohamad Farhana, N.K. Omar, Fatin Saiha Algaradah, Mohammed M. Bashir, Shahid Ramesh, Subramaniam Ramesh, Kasi Q Science (General) QC Physics 1-Methyl-3-propylimidazolium iodide (MPII) ionic liquid incorporated gel polymer electrolyte (GPE) has successfully enhanced the efficiency of a dye-sensitized solar cell (DSSC). A series of gel polymer electrolytes containing different amounts of MPII were prepared and characterized. A maximum ionic conductivity of 3.99 mS cm−1 was obtained in a GPE containing 10 wt% MPII, which was accompanied by the lowest activation energy. The results from dielectric studies showed typical behaviour for both ɛ’ and ɛ” in which their values decreased with increasing frequency but increased proportionately with temperature. From the results of FESEM, the morphologies of the GPE became slightly rougher after the addition of MPII. Dye-sensitized solar cells were fabricated and characterized using electrochemical impedance spectroscopy (EIS) and photovoltaic studies. DSSC with the best performance (4.35% of efficiency, 9.97 mA cm−2 of JSC, 0.67 V of VOC, and 65.39% of fill factor) was assembled using the GPE with 10 wt% of MPII. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature. Springer Verlag (Germany) 2020 Article PeerReviewed Tan, Chee Yu and Saidi, Norshahirah Mohamad and Farhana, N.K. and Omar, Fatin Saiha and Algaradah, Mohammed M. and Bashir, Shahid and Ramesh, Subramaniam and Ramesh, Kasi (2020) Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide. Ionics, 26 (6). pp. 3173-3183. ISSN 0947-7047, DOI https://doi.org/10.1007/s11581-020-03447-2 <https://doi.org/10.1007/s11581-020-03447-2>. https://doi.org/10.1007/s11581-020-03447-2 doi:10.1007/s11581-020-03447-2
spellingShingle Q Science (General)
QC Physics
Tan, Chee Yu
Saidi, Norshahirah Mohamad
Farhana, N.K.
Omar, Fatin Saiha
Algaradah, Mohammed M.
Bashir, Shahid
Ramesh, Subramaniam
Ramesh, Kasi
Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide
title Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide
title_full Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide
title_fullStr Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide
title_full_unstemmed Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide
title_short Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide
title_sort improved ionic conductivity and efficiency of dye sensitized solar cells with the incorporation of 1 methyl 3 propylimidazolium iodide
topic Q Science (General)
QC Physics
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