1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph
The title compound, C(13)H(10)Cl(2)N(2)S, represents a monoclinic polymorph of the previously reported ortho-rhom-bic form [Ramnathan et al. (1996 ▶). Acta Cryst. C52, 134-136]. The mol-ecule is twisted with the dihedral angle between the benzene rings being 55.37 (7)°. The N-H atoms are syn to each...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/3464/1/26.pdf |
| _version_ | 1825718807513006080 |
|---|---|
| author | Yeo, C.I. Tiekink, E.R. |
| author_facet | Yeo, C.I. Tiekink, E.R. |
| author_sort | Yeo, C.I. |
| collection | UM |
| description | The title compound, C(13)H(10)Cl(2)N(2)S, represents a monoclinic polymorph of the previously reported ortho-rhom-bic form [Ramnathan et al. (1996 ▶). Acta Cryst. C52, 134-136]. The mol-ecule is twisted with the dihedral angle between the benzene rings being 55.37 (7)°. The N-H atoms are syn to each other, which contrasts their anti disposition in the ortho-rhom-bic form. In the crystal, mol-ecules assemble into zigzag chains along the c axis via N-H⋯S hydrogen bonds. Chains are connected into layers via C-H⋯Cl inter-actions, and these stack along the a axis. |
| first_indexed | 2024-03-06T05:09:59Z |
| format | Article |
| id | um.eprints-3464 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:09:59Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-34642019-01-30T08:03:28Z http://eprints.um.edu.my/3464/ 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph Yeo, C.I. Tiekink, E.R. QD Chemistry R Medicine The title compound, C(13)H(10)Cl(2)N(2)S, represents a monoclinic polymorph of the previously reported ortho-rhom-bic form [Ramnathan et al. (1996 ▶). Acta Cryst. C52, 134-136]. The mol-ecule is twisted with the dihedral angle between the benzene rings being 55.37 (7)°. The N-H atoms are syn to each other, which contrasts their anti disposition in the ortho-rhom-bic form. In the crystal, mol-ecules assemble into zigzag chains along the c axis via N-H⋯S hydrogen bonds. Chains are connected into layers via C-H⋯Cl inter-actions, and these stack along the a axis. International Union of Crystallography 2011-11 Article PeerReviewed application/pdf en http://eprints.um.edu.my/3464/1/26.pdf Yeo, C.I. and Tiekink, E.R. (2011) 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph. Acta Crystallographica Section E: Structure Reports Online, 67 (pt11). ISSN 1600-5368, DOI PMID: 22219989. http://www.ncbi.nlm.nih.gov/pubmed/22219989 PMID: 22219989 |
| spellingShingle | QD Chemistry R Medicine Yeo, C.I. Tiekink, E.R. 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph |
| title | 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph |
| title_full | 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph |
| title_fullStr | 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph |
| title_full_unstemmed | 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph |
| title_short | 1,3-Bis(2-chloro-phen-yl)thio-urea: a monoclinic polymorph |
| title_sort | 1 3 bis 2 chloro phen yl thio urea a monoclinic polymorph |
| topic | QD Chemistry R Medicine |
| url | http://eprints.um.edu.my/3464/1/26.pdf |
| work_keys_str_mv | AT yeoci 13bis2chlorophenylthioureaamonoclinicpolymorph AT tiekinker 13bis2chlorophenylthioureaamonoclinicpolymorph |