Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II)
The asymmetric unit of the title compound, [Pd(C12H12NO)(2)], consists of three crystallographically independent half-molecules. Each Pd-II atom lies on a center of inversion and is four-coordinated by two monoanionic forms of the aminoacrylaldehyde in a square-planar geometry. In the crystal, adjac...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5218/1/Khaledi-2011-Bis_3%2C3-dimethyl-2-%28.pdf |
| _version_ | 1825719056912613376 |
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| author | Khaledi, H. Ali, Hapipah Mohd Olmstead, M.M. |
| author_facet | Khaledi, H. Ali, Hapipah Mohd Olmstead, M.M. |
| author_sort | Khaledi, H. |
| collection | UM |
| description | The asymmetric unit of the title compound, [Pd(C12H12NO)(2)], consists of three crystallographically independent half-molecules. Each Pd-II atom lies on a center of inversion and is four-coordinated by two monoanionic forms of the aminoacrylaldehyde in a square-planar geometry. In the crystal, adjacent molecules are connected through C-H center dot center dot center dot pi and C-H center dot center dot center dot O interactions into a three-dimensional polymeric structure. |
| first_indexed | 2024-03-06T05:13:50Z |
| format | Article |
| id | um.eprints-5218 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:50Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52182019-01-30T01:04:26Z http://eprints.um.edu.my/5218/ Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II) Khaledi, H. Ali, Hapipah Mohd Olmstead, M.M. QD Chemistry The asymmetric unit of the title compound, [Pd(C12H12NO)(2)], consists of three crystallographically independent half-molecules. Each Pd-II atom lies on a center of inversion and is four-coordinated by two monoanionic forms of the aminoacrylaldehyde in a square-planar geometry. In the crystal, adjacent molecules are connected through C-H center dot center dot center dot pi and C-H center dot center dot center dot O interactions into a three-dimensional polymeric structure. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5218/1/Khaledi-2011-Bis_3%2C3-dimethyl-2-%28.pdf Khaledi, H. and Ali, Hapipah Mohd and Olmstead, M.M. (2011) Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II). Acta Crystallographica Section E: Structure Reports Online, 67. M929-U1020. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811022069 <https://doi.org/10.1107/s1600536811022069>. http://scripts.iucr.org/cgi-bin/paper?S1600536811022069 10.1107/s1600536811022069 |
| spellingShingle | QD Chemistry Khaledi, H. Ali, Hapipah Mohd Olmstead, M.M. Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II) |
| title | Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II) |
| title_full | Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II) |
| title_fullStr | Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II) |
| title_full_unstemmed | Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II) |
| title_short | Bis 3,3-dimethyl-2-(2-oxoethylidene)indolinyl-kappa N-2,O palladium(II) |
| title_sort | bis 3 3 dimethyl 2 2 oxoethylidene indolinyl kappa n 2 o palladium ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5218/1/Khaledi-2011-Bis_3%2C3-dimethyl-2-%28.pdf |
| work_keys_str_mv | AT khaledih bis33dimethyl22oxoethylideneindolinylkappan2opalladiumii AT alihapipahmohd bis33dimethyl22oxoethylideneindolinylkappan2opalladiumii AT olmsteadmm bis33dimethyl22oxoethylideneindolinylkappan2opalladiumii |