Dipotassium disulfanilamidate trihydrate

The asymmetric unit of the title compound, 2K(+)center dot-2C(6)H(7)N(2)O(2)S(-)center dot 3H(2)O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One po...

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Main Authors: How, F.N.F., Ali, Hapipah Mohd, Khaledi, H., Rahima, Z.A.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
Online Access:http://eprints.um.edu.my/5230/1/How-2011-Dipotassium_disulfan.pdf
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author How, F.N.F.
Ali, Hapipah Mohd
Khaledi, H.
Rahima, Z.A.
author_facet How, F.N.F.
Ali, Hapipah Mohd
Khaledi, H.
Rahima, Z.A.
author_sort How, F.N.F.
collection UM
description The asymmetric unit of the title compound, 2K(+)center dot-2C(6)H(7)N(2)O(2)S(-)center dot 3H(2)O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One potassium cation is seven-coordinated by six sulfonyl O atoms and one water molecule, whereas the other is surrounded by six water O atoms and two sulfonyl O atoms. In the crystal structure, the components are connected into polymeric sheets in the bc plane. The two-dimensional structure is consolidated by N-H center dot center dot center dot O, O-H center dot center dot center dot O, O-H center dot center dot center dot N and C-H center dot center dot center dot pi interactions. The layers are further linked into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot N and O-H center dot center dot center dot N hydrogen bonds.
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spelling um.eprints-52302019-01-30T01:00:37Z http://eprints.um.edu.my/5230/ Dipotassium disulfanilamidate trihydrate How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Rahima, Z.A. QD Chemistry The asymmetric unit of the title compound, 2K(+)center dot-2C(6)H(7)N(2)O(2)S(-)center dot 3H(2)O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One potassium cation is seven-coordinated by six sulfonyl O atoms and one water molecule, whereas the other is surrounded by six water O atoms and two sulfonyl O atoms. In the crystal structure, the components are connected into polymeric sheets in the bc plane. The two-dimensional structure is consolidated by N-H center dot center dot center dot O, O-H center dot center dot center dot O, O-H center dot center dot center dot N and C-H center dot center dot center dot pi interactions. The layers are further linked into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot N and O-H center dot center dot center dot N hydrogen bonds. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5230/1/How-2011-Dipotassium_disulfan.pdf How, F.N.F. and Ali, Hapipah Mohd and Khaledi, H. and Rahima, Z.A. (2011) Dipotassium disulfanilamidate trihydrate. Acta Crystallographica Section E: Structure Reports Online, 67. M1071-U643. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811026791 <https://doi.org/10.1107/s1600536811026791>. http://scripts.iucr.org/cgi-bin/paper?S1600536811026791 10.1107/s1600536811026791
spellingShingle QD Chemistry
How, F.N.F.
Ali, Hapipah Mohd
Khaledi, H.
Rahima, Z.A.
Dipotassium disulfanilamidate trihydrate
title Dipotassium disulfanilamidate trihydrate
title_full Dipotassium disulfanilamidate trihydrate
title_fullStr Dipotassium disulfanilamidate trihydrate
title_full_unstemmed Dipotassium disulfanilamidate trihydrate
title_short Dipotassium disulfanilamidate trihydrate
title_sort dipotassium disulfanilamidate trihydrate
topic QD Chemistry
url http://eprints.um.edu.my/5230/1/How-2011-Dipotassium_disulfan.pdf
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AT alihapipahmohd dipotassiumdisulfanilamidatetrihydrate
AT khaledih dipotassiumdisulfanilamidatetrihydrate
AT rahimaza dipotassiumdisulfanilamidatetrihydrate