Dipotassium disulfanilamidate trihydrate
The asymmetric unit of the title compound, 2K(+)center dot-2C(6)H(7)N(2)O(2)S(-)center dot 3H(2)O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One po...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011
|
Subjects: | |
Online Access: | http://eprints.um.edu.my/5230/1/How-2011-Dipotassium_disulfan.pdf |
_version_ | 1796945250870099968 |
---|---|
author | How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Rahima, Z.A. |
author_facet | How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Rahima, Z.A. |
author_sort | How, F.N.F. |
collection | UM |
description | The asymmetric unit of the title compound, 2K(+)center dot-2C(6)H(7)N(2)O(2)S(-)center dot 3H(2)O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One potassium cation is seven-coordinated by six sulfonyl O atoms and one water molecule, whereas the other is surrounded by six water O atoms and two sulfonyl O atoms. In the crystal structure, the components are connected into polymeric sheets in the bc plane. The two-dimensional structure is consolidated by N-H center dot center dot center dot O, O-H center dot center dot center dot O, O-H center dot center dot center dot N and C-H center dot center dot center dot pi interactions. The layers are further linked into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot N and O-H center dot center dot center dot N hydrogen bonds. |
first_indexed | 2024-03-06T05:13:51Z |
format | Article |
id | um.eprints-5230 |
institution | Universiti Malaya |
language | English |
last_indexed | 2024-03-06T05:13:51Z |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | dspace |
spelling | um.eprints-52302019-01-30T01:00:37Z http://eprints.um.edu.my/5230/ Dipotassium disulfanilamidate trihydrate How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Rahima, Z.A. QD Chemistry The asymmetric unit of the title compound, 2K(+)center dot-2C(6)H(7)N(2)O(2)S(-)center dot 3H(2)O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One potassium cation is seven-coordinated by six sulfonyl O atoms and one water molecule, whereas the other is surrounded by six water O atoms and two sulfonyl O atoms. In the crystal structure, the components are connected into polymeric sheets in the bc plane. The two-dimensional structure is consolidated by N-H center dot center dot center dot O, O-H center dot center dot center dot O, O-H center dot center dot center dot N and C-H center dot center dot center dot pi interactions. The layers are further linked into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot N and O-H center dot center dot center dot N hydrogen bonds. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5230/1/How-2011-Dipotassium_disulfan.pdf How, F.N.F. and Ali, Hapipah Mohd and Khaledi, H. and Rahima, Z.A. (2011) Dipotassium disulfanilamidate trihydrate. Acta Crystallographica Section E: Structure Reports Online, 67. M1071-U643. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811026791 <https://doi.org/10.1107/s1600536811026791>. http://scripts.iucr.org/cgi-bin/paper?S1600536811026791 10.1107/s1600536811026791 |
spellingShingle | QD Chemistry How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Rahima, Z.A. Dipotassium disulfanilamidate trihydrate |
title | Dipotassium disulfanilamidate trihydrate |
title_full | Dipotassium disulfanilamidate trihydrate |
title_fullStr | Dipotassium disulfanilamidate trihydrate |
title_full_unstemmed | Dipotassium disulfanilamidate trihydrate |
title_short | Dipotassium disulfanilamidate trihydrate |
title_sort | dipotassium disulfanilamidate trihydrate |
topic | QD Chemistry |
url | http://eprints.um.edu.my/5230/1/How-2011-Dipotassium_disulfan.pdf |
work_keys_str_mv | AT howfnf dipotassiumdisulfanilamidatetrihydrate AT alihapipahmohd dipotassiumdisulfanilamidatetrihydrate AT khaledih dipotassiumdisulfanilamidatetrihydrate AT rahimaza dipotassiumdisulfanilamidatetrihydrate |