4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1)
In the title compound, C(6)H(6)N(2)O center dot C(8)H(8)O(3), an equimolar co-crystal of nicotinamide and vanillin, the aromatic ring and the amide fragment of the nicotinamide molecule make a dihedral angle of 32.6 (2)degrees. The vanillin molecule is almost planar, with an r.m.s. deviation for all...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5231/1/How-2011-4-Hydroxy-3-methoxyb.pdf |
| _version_ | 1825719058894422016 |
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| author | How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Amalina, M.S. |
| author_facet | How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Amalina, M.S. |
| author_sort | How, F.N.F. |
| collection | UM |
| description | In the title compound, C(6)H(6)N(2)O center dot C(8)H(8)O(3), an equimolar co-crystal of nicotinamide and vanillin, the aromatic ring and the amide fragment of the nicotinamide molecule make a dihedral angle of 32.6 (2)degrees. The vanillin molecule is almost planar, with an r.m.s. deviation for all non-H atoms of 0.0094 angstrom. The vaniline and nicotinamide aromatic rings are nearly coplanar, the dihedral angle between them being 3.20 (9)degrees. In the crystal, the two components are linked through N-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds into chains along the a axis. The chains are connected via C-H center dot center dot center dot O interactions, forming a three-dimensional polymeric structure. |
| first_indexed | 2024-03-06T05:13:51Z |
| format | Article |
| id | um.eprints-5231 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:51Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52312019-01-30T01:13:42Z http://eprints.um.edu.my/5231/ 4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1) How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Amalina, M.S. QD Chemistry In the title compound, C(6)H(6)N(2)O center dot C(8)H(8)O(3), an equimolar co-crystal of nicotinamide and vanillin, the aromatic ring and the amide fragment of the nicotinamide molecule make a dihedral angle of 32.6 (2)degrees. The vanillin molecule is almost planar, with an r.m.s. deviation for all non-H atoms of 0.0094 angstrom. The vaniline and nicotinamide aromatic rings are nearly coplanar, the dihedral angle between them being 3.20 (9)degrees. In the crystal, the two components are linked through N-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds into chains along the a axis. The chains are connected via C-H center dot center dot center dot O interactions, forming a three-dimensional polymeric structure. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5231/1/How-2011-4-Hydroxy-3-methoxyb.pdf How, F.N.F. and Ali, Hapipah Mohd and Khaledi, H. and Amalina, M.S. (2011) 4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1). Acta Crystallographica Section E: Structure Reports Online, 67. O3168-U173. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811045648 <https://doi.org/10.1107/s1600536811045648>. http://scripts.iucr.org/cgi-bin/paper?S1600536811045648 10.1107/s1600536811045648 |
| spellingShingle | QD Chemistry How, F.N.F. Ali, Hapipah Mohd Khaledi, H. Amalina, M.S. 4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1) |
| title | 4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1) |
| title_full | 4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1) |
| title_fullStr | 4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1) |
| title_full_unstemmed | 4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1) |
| title_short | 4-Hydroxy-3-methoxybenzaldehyde-nicotinamide(1/1) |
| title_sort | 4 hydroxy 3 methoxybenzaldehyde nicotinamide 1 1 |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5231/1/How-2011-4-Hydroxy-3-methoxyb.pdf |
| work_keys_str_mv | AT howfnf 4hydroxy3methoxybenzaldehydenicotinamide11 AT alihapipahmohd 4hydroxy3methoxybenzaldehydenicotinamide11 AT khaledih 4hydroxy3methoxybenzaldehydenicotinamide11 AT amalinams 4hydroxy3methoxybenzaldehydenicotinamide11 |