Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc
In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination en...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | http://eprints.um.edu.my/5232/1/Hisham-2011-Dichlorido%282-%7B_3-%28mo.pdf |
| _version_ | 1825719059089457152 |
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| author | Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. |
| author_facet | Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. |
| author_sort | Hisham, N.A.I. |
| collection | UM |
| description | In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination environment. In the crystal, a pair of N-H center dot center dot center dot O hydrogen bonds connect the molecules into a centrosymmetric dimer. C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also observed. |
| first_indexed | 2024-03-06T05:13:52Z |
| format | Article |
| id | um.eprints-5232 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:52Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52322019-01-30T00:55:42Z http://eprints.um.edu.my/5232/ Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. QD Chemistry In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination environment. In the crystal, a pair of N-H center dot center dot center dot O hydrogen bonds connect the molecules into a centrosymmetric dimer. C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also observed. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5232/1/Hisham-2011-Dichlorido%282-%7B_3-%28mo.pdf Hisham, N.A.I. and Ali, Hapipah Mohd and Khaledi, H. (2011) Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc. Acta Crystallographica Section E: Structure Reports Online, 67. M932-U1048. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811022021 <https://doi.org/10.1107/s1600536811022021>. http://scripts.iucr.org/cgi-bin/paper?S1600536811022021 10.1107/s1600536811022021 |
| spellingShingle | QD Chemistry Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_full | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_fullStr | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_full_unstemmed | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_short | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_sort | dichlorido 2 3 morpholin 4 ium 4 yl propyl iminomethyl phenolate zinc |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5232/1/Hisham-2011-Dichlorido%282-%7B_3-%28mo.pdf |
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