Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II)
In the title compound, [MnCl2(C13H19N3O)], the Mn-II ion is pentacoordinated in a distorted square-pyramidal geometry. The coordination environment is defined by the N,N',N ''-tridentate Schiff base ligand and one Cl atom in the basal positions and one Cl atom in the apical position....
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5235/1/Hisham-2011-Dichlorido%7B2-morphol.pdf |
| _version_ | 1796945251876732928 |
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| author | Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. Gwaram, N.S. |
| author_facet | Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. Gwaram, N.S. |
| author_sort | Hisham, N.A.I. |
| collection | UM |
| description | In the title compound, [MnCl2(C13H19N3O)], the Mn-II ion is pentacoordinated in a distorted square-pyramidal geometry. The coordination environment is defined by the N,N',N ''-tridentate Schiff base ligand and one Cl atom in the basal positions and one Cl atom in the apical position. In the crystal, intermolecular C-H center dot center dot center dot Cl hydrogen bonds link the molecules into a three-dimensional network. An intramolecular C-H center dot center dot center dot Cl hydrogen bond is also observed. |
| first_indexed | 2024-03-06T05:13:52Z |
| format | Article |
| id | um.eprints-5235 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:52Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52352019-01-30T00:57:21Z http://eprints.um.edu.my/5235/ Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II) Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. Gwaram, N.S. QD Chemistry In the title compound, [MnCl2(C13H19N3O)], the Mn-II ion is pentacoordinated in a distorted square-pyramidal geometry. The coordination environment is defined by the N,N',N ''-tridentate Schiff base ligand and one Cl atom in the basal positions and one Cl atom in the apical position. In the crystal, intermolecular C-H center dot center dot center dot Cl hydrogen bonds link the molecules into a three-dimensional network. An intramolecular C-H center dot center dot center dot Cl hydrogen bond is also observed. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5235/1/Hisham-2011-Dichlorido%7B2-morphol.pdf Hisham, N.A.I. and Ali, Hapipah Mohd and Khaledi, H. and Gwaram, N.S. (2011) Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II). Acta Crystallographica Section E: Structure Reports Online, 67. M41-U515. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810050221 <https://doi.org/10.1107/s1600536810050221>. http://scripts.iucr.org/cgi-bin/paper?S1600536810050221 10.1107/s1600536810050221 |
| spellingShingle | QD Chemistry Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. Gwaram, N.S. Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II) |
| title | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II) |
| title_full | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II) |
| title_fullStr | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II) |
| title_full_unstemmed | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II) |
| title_short | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}manganese(II) |
| title_sort | dichlorido 2 morpholino n 1 2 pyridyl ethylidene ethanamine kappa n 3 n n manganese ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5235/1/Hisham-2011-Dichlorido%7B2-morphol.pdf |
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