Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II)

Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II)

In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N',N ''-tridentate chelating agent, making two five-membered rings with the Zn-II ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry....

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Bibliographic Details
Main Authors: Hisham, N.A.I., Gwaram, N.S., Khaledi, H., Ali, Hapipah Mohd
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5236/1/Hisham-2011-Dichlorido%7B2-morphol.pdf
Description
Summary:In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N',N ''-tridentate chelating agent, making two five-membered rings with the Zn-II ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intramolecular C-H center dot center dot center dot Cl interaction occurs. In the crystal, adjacent molecules are linked together via C-H center dot center dot center dot Cl hydrogen-bonding and long range C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions into a three-dimensional network.

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