Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II)
In the title compound, [Ni(NCS)(2)(C11H17N3)(H2O)], the NiII ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothiocyanate groups and one water molecule. In the crystal, O-H...S hydrogen bonds link adjacent molecules into infinite layers pa...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | http://eprints.um.edu.my/5240/1/Gwaram-2011-Aqua%7BN%2CN-dimethyl-N.pdf |
| _version_ | 1825719060656029696 |
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| author | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Saharin, S.M. |
| author_facet | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Saharin, S.M. |
| author_sort | Gwaram, N.S. |
| collection | UM |
| description | In the title compound, [Ni(NCS)(2)(C11H17N3)(H2O)], the NiII ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothiocyanate groups and one water molecule. In the crystal, O-H...S hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-H...pi interactions. The -CH2-N(CH3)(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio. |
| first_indexed | 2024-03-06T05:13:53Z |
| format | Article |
| id | um.eprints-5240 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:53Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52402019-01-31T04:13:06Z http://eprints.um.edu.my/5240/ Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II) Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Saharin, S.M. QD Chemistry In the title compound, [Ni(NCS)(2)(C11H17N3)(H2O)], the NiII ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothiocyanate groups and one water molecule. In the crystal, O-H...S hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-H...pi interactions. The -CH2-N(CH3)(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5240/1/Gwaram-2011-Aqua%7BN%2CN-dimethyl-N.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Saharin, S.M. (2011) Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II). Acta Crystallographica Section E: Structure Reports Online, 67. M513-U1123. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811011512 <https://doi.org/10.1107/s1600536811011512>. http://scripts.iucr.org/cgi-bin/paper?S1600536811011512 10.1107/s1600536811011512 |
| spellingShingle | QD Chemistry Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Saharin, S.M. Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II) |
| title | Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II) |
| title_full | Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II) |
| title_fullStr | Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II) |
| title_full_unstemmed | Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II) |
| title_short | Aqua{N,N-dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa 3 N,N ',N ''}bis(thiocyanato-kappa N)nickel(II) |
| title_sort | aqua n n dimethyl n 1 2 pyridyl ethylidene ethane 1 2 diamine kappa 3 n n n bis thiocyanato kappa n nickel ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5240/1/Gwaram-2011-Aqua%7BN%2CN-dimethyl-N.pdf |
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