Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium
In the title compound, [CdCl2(C11H17N3)], the Schiff base acts as an N,N',N ''-tridentate ligand towards the Cd-II ion. Two Cl atoms complete a distorted square-pyramidal geometry around the metal atom. In the crystal, a C-H center dot center dot center dot Cl interaction connects pai...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2011
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Online Access: | http://eprints.um.edu.my/5244/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf |
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author | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
author_facet | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
author_sort | Gwaram, N.S. |
collection | UM |
description | In the title compound, [CdCl2(C11H17N3)], the Schiff base acts as an N,N',N ''-tridentate ligand towards the Cd-II ion. Two Cl atoms complete a distorted square-pyramidal geometry around the metal atom. In the crystal, a C-H center dot center dot center dot Cl interaction connects pairs of molecules into centrosymetric dimers. |
first_indexed | 2024-03-06T05:13:54Z |
format | Article |
id | um.eprints-5244 |
institution | Universiti Malaya |
language | English |
last_indexed | 2024-03-06T05:13:54Z |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | dspace |
spelling | um.eprints-52442019-01-30T00:59:23Z http://eprints.um.edu.my/5244/ Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. QD Chemistry In the title compound, [CdCl2(C11H17N3)], the Schiff base acts as an N,N',N ''-tridentate ligand towards the Cd-II ion. Two Cl atoms complete a distorted square-pyramidal geometry around the metal atom. In the crystal, a C-H center dot center dot center dot Cl interaction connects pairs of molecules into centrosymetric dimers. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5244/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium. Acta Crystallographica Section E: Structure Reports Online, 67. M348-U642. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811005538 <https://doi.org/10.1107/s1600536811005538>. http://scripts.iucr.org/cgi-bin/paper?S1600536811005538 10.1107/s1600536811005538 |
spellingShingle | QD Chemistry Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium |
title | Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium |
title_full | Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium |
title_fullStr | Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium |
title_full_unstemmed | Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium |
title_short | Dichlorido{N,N-dimethyl-N '- 1-(pyridin-2-yl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}cadmium |
title_sort | dichlorido n n dimethyl n 1 pyridin 2 yl ethylidene ethane 1 2 diamine kappa n 3 n n cadmium |
topic | QD Chemistry |
url | http://eprints.um.edu.my/5244/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf |
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