Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate
In the title compound, [CuCl2(C13H19N3O)]center dot H2O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu-II ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the a...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5245/1/Gwaram-2011-Dichlorido%7B2-%28morpho.pdf |
| _version_ | 1825719061637496832 |
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| author | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
| author_facet | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
| author_sort | Gwaram, N.S. |
| collection | UM |
| description | In the title compound, [CuCl2(C13H19N3O)]center dot H2O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu-II ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O-H center dot center dot center dot Cl hydrogen bonds link the complex molecules and the uncoordinated water molecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions. |
| first_indexed | 2024-03-06T05:13:54Z |
| format | Article |
| id | um.eprints-5245 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:54Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52452019-01-31T04:12:47Z http://eprints.um.edu.my/5245/ Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. QD Chemistry In the title compound, [CuCl2(C13H19N3O)]center dot H2O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu-II ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O-H center dot center dot center dot Cl hydrogen bonds link the complex molecules and the uncoordinated water molecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5245/1/Gwaram-2011-Dichlorido%7B2-%28morpho.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate. Acta Crystallographica Section E: Structure Reports Online, 67. M334-U503. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811004892 <https://doi.org/10.1107/s1600536811004892>. http://journals.iucr.org/e/issues/2011/03/00/is2674/is2674.pdf 10.1107/s1600536811004892 |
| spellingShingle | QD Chemistry Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate |
| title | Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate |
| title_full | Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate |
| title_fullStr | Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate |
| title_full_unstemmed | Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate |
| title_short | Dichlorido{2-(morpholin-4-yl)-N- 1-(pyridin-2-yl)ethylidene ethanamine-k appa N-3,N ',N ''}copper(II) monohydrate |
| title_sort | dichlorido 2 morpholin 4 yl n 1 pyridin 2 yl ethylidene ethanamine k appa n 3 n n copper ii monohydrate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5245/1/Gwaram-2011-Dichlorido%7B2-%28morpho.pdf |
| work_keys_str_mv | AT gwaramns dichlorido2morpholin4yln1pyridin2ylethylideneethanaminekappan3nncopperiimonohydrate AT alihapipahmohd dichlorido2morpholin4yln1pyridin2ylethylideneethanaminekappan3nncopperiimonohydrate AT khaledih dichlorido2morpholin4yln1pyridin2ylethylideneethanaminekappan3nncopperiimonohydrate |