{N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II)
The asymmetric unit of the title compound, [Cu(NCS)(2)(C11H17N3)], consists of two crystallographically independent molecules. In each molecule, the Cu-II ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N ''-tridentate Sc...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | http://eprints.um.edu.my/5250/1/Gwaram-2011-%7BN%2CN-Dimethyl-N_%27-_1.pdf |
| _version_ | 1796945254859931648 |
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| author | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
| author_facet | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
| author_sort | Gwaram, N.S. |
| collection | UM |
| description | The asymmetric unit of the title compound, [Cu(NCS)(2)(C11H17N3)], consists of two crystallographically independent molecules. In each molecule, the Cu-II ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N ''-tridentate Schiff base and one N-bound thiocyanate ligand. The second N-donor thiocyanate group, located at the apical site, completes the coordination environment. In the crystal, intermolecular C-H center dot center dot center dot S and C-H center dot center dot center dot N hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. Intramolecular C-H center dot center dot center dot N interactions are also observed. |
| first_indexed | 2024-03-06T05:13:55Z |
| format | Article |
| id | um.eprints-5250 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:55Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52502019-01-30T00:47:53Z http://eprints.um.edu.my/5250/ {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. QD Chemistry The asymmetric unit of the title compound, [Cu(NCS)(2)(C11H17N3)], consists of two crystallographically independent molecules. In each molecule, the Cu-II ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N ''-tridentate Schiff base and one N-bound thiocyanate ligand. The second N-donor thiocyanate group, located at the apical site, completes the coordination environment. In the crystal, intermolecular C-H center dot center dot center dot S and C-H center dot center dot center dot N hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. Intramolecular C-H center dot center dot center dot N interactions are also observed. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5250/1/Gwaram-2011-%7BN%2CN-Dimethyl-N_%27-_1.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II). Acta Crystallographica Section E: Structure Reports Online, 67. M930-U1031. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811022057 <https://doi.org/10.1107/s1600536811022057>. http://scripts.iucr.org/cgi-bin/paper?S1600536811022057 10.1107/s1600536811022057 |
| spellingShingle | QD Chemistry Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title | {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_full | {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_fullStr | {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_full_unstemmed | {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_short | {N,N-Dimethyl-N '- 1-(2-pyridyl)ethylidene ethane-1,2-diamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_sort | n n dimethyl n 1 2 pyridyl ethylidene ethane 1 2 diamine kappa n 3 n n bis thiocyanato kappa n copper ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5250/1/Gwaram-2011-%7BN%2CN-Dimethyl-N_%27-_1.pdf |
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