Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc
The asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate Zn-II complex molecules. In each molecule, the metal atom is coordinated by an N,N ',N ''-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two mol...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | http://eprints.um.edu.my/5254/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf |
| _version_ | 1825719063468310528 |
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| author | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
| author_facet | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
| author_sort | Gwaram, N.S. |
| collection | UM |
| description | The asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate Zn-II complex molecules. In each molecule, the metal atom is coordinated by an N,N ',N ''-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecules differ little in their geometry, but more in their intermolecular interactions. In the crystal, adjacent molecules are connected via C-H center dot center dot center dot Cl interactions into a three-dimensional supramolecular structure. The network is supplemented by pi-pi interactions formed between the aromatic rings of pairs of the symmetry-related molecules [centroid-centroid distances = 3.6255 (10) and 3.7073 (10) angstrom]. The crystal lattice contains void spaces with a size of 52 angstrom(3). |
| first_indexed | 2024-03-06T05:13:56Z |
| format | Article |
| id | um.eprints-5254 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:56Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52542019-01-30T00:58:54Z http://eprints.um.edu.my/5254/ Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. QD Chemistry The asymmetric unit of the title compound, [ZnCl2(C11H17N3)], contains two independent pentacoordinate Zn-II complex molecules. In each molecule, the metal atom is coordinated by an N,N ',N ''-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two molecules differ little in their geometry, but more in their intermolecular interactions. In the crystal, adjacent molecules are connected via C-H center dot center dot center dot Cl interactions into a three-dimensional supramolecular structure. The network is supplemented by pi-pi interactions formed between the aromatic rings of pairs of the symmetry-related molecules [centroid-centroid distances = 3.6255 (10) and 3.7073 (10) angstrom]. The crystal lattice contains void spaces with a size of 52 angstrom(3). International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5254/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2011) Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc. Acta Crystallographica Section E: Structure Reports Online, 67. M1027-U291. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811025669 <https://doi.org/10.1107/s1600536811025669>. http://journals.iucr.org/e/issues/2011/08/00/om2444/om2444.pdf 10.1107/s1600536811025669 |
| spellingShingle | QD Chemistry Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc |
| title | Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc |
| title_full | Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc |
| title_fullStr | Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc |
| title_full_unstemmed | Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc |
| title_short | Dichlorido{N,N-dimethyl-N '- 1-(2pyridyl) ethylidene ethane-1,2-diamine-k(3) N,N ',N ''}zinc |
| title_sort | dichlorido n n dimethyl n 1 2pyridyl ethylidene ethane 1 2 diamine k 3 n n n zinc |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5254/1/Gwaram-2011-Dichlorido%7BN%2CN-dimet.pdf |
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