Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II)
In the title complex, [Co(NCS)(2)(C13H19N3O)(H2O)], the Co-II ion is six-coordinated by the N,N',N ''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water molecule in a distorted octahedral geometry. Intramolecular C-H center dot center dot center dot N and C-H...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | http://eprints.um.edu.my/5256/1/Gwaram-2011-Aqua%7B2-morpholino-N-.pdf |
| _version_ | 1825719063875158016 |
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| author | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. |
| author_facet | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. |
| author_sort | Gwaram, N.S. |
| collection | UM |
| description | In the title complex, [Co(NCS)(2)(C13H19N3O)(H2O)], the Co-II ion is six-coordinated by the N,N',N ''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water molecule in a distorted octahedral geometry. Intramolecular C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds occur. In the crystal, intermolecular O-H center dot center dot center dot O, O-H center dot center dot center dot S, C-H center dot center dot center dot S and S center dot center dot center dot S [3.5546 (18) angstrom] interactions result in an infinite three-dimensional network. |
| first_indexed | 2024-03-06T05:13:56Z |
| format | Article |
| id | um.eprints-5256 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:56Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52562019-01-30T01:02:33Z http://eprints.um.edu.my/5256/ Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II) Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. QD Chemistry In the title complex, [Co(NCS)(2)(C13H19N3O)(H2O)], the Co-II ion is six-coordinated by the N,N',N ''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water molecule in a distorted octahedral geometry. Intramolecular C-H center dot center dot center dot N and C-H center dot center dot center dot O hydrogen bonds occur. In the crystal, intermolecular O-H center dot center dot center dot O, O-H center dot center dot center dot S, C-H center dot center dot center dot S and S center dot center dot center dot S [3.5546 (18) angstrom] interactions result in an infinite three-dimensional network. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5256/1/Gwaram-2011-Aqua%7B2-morpholino-N-.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Hisham, N.A.I. (2011) Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II). Acta Crystallographica Section E: Structure Reports Online. M205-U885. ISSN 1600-5368, DOI https://doi.org/10.1107/s160053681100136x <https://doi.org/10.1107/s160053681100136x>. http://scripts.iucr.org/cgi-bin/paper?S160053681100136X 10.1107/s160053681100136x |
| spellingShingle | QD Chemistry Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II) |
| title | Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II) |
| title_full | Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II) |
| title_fullStr | Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II) |
| title_full_unstemmed | Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II) |
| title_short | Aqua{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)cobalt(II) |
| title_sort | aqua 2 morpholino n 1 2 pyridyl ethylidene ethanamine kappa n 3 n n bis thiocyanato kappa n cobalt ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5256/1/Gwaram-2011-Aqua%7B2-morpholino-N-.pdf |
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