{2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)zinc(II)

{2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)zinc(II)

The asymmetric unit of the title compound, [Zn(NCS)(2)(C13H19N3O)], contains two crystallographically independent molecules. In each molecule, the Zn-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two thiocyanate ligands in a distorted square-pyr...

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Bibliographic Details
Main Authors: Gwaram, N.S., Ali, Hapipah Mohd, Khaledi, H., Hisham, N.A.I.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Subjects:
QD Chemistry
Online Access:http://eprints.um.edu.my/5257/1/Gwaram-2011-%7B2-Morpholino-N-_1-%28.pdf
Description
Summary:The asymmetric unit of the title compound, [Zn(NCS)(2)(C13H19N3O)], contains two crystallographically independent molecules. In each molecule, the Zn-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two thiocyanate ligands in a distorted square-pyramidal geometry. The two molecules differ mainly in the deviations from the ideal geometry, with tau values of 0.14 and 0.33. In the crystal, intermolecular C-H center dot center dot center dot S hydrogen bonds are observed. An intramolecular C-H center dot center dot center dot N hydrogen bond occurs in one of the independent molecules.

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