Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II)
In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is pentacoordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)ethyl] iminomethyl} phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformati...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Online Access: | http://eprints.um.edu.my/5273/1/Salga-2010-Dichlorido%282-%7B_2-%28pi.pdf |
| _version_ | 1825719066779713536 |
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| author | Salga, M.S. Ali, Hapipah Mohd Khaledi, H. |
| author_facet | Salga, M.S. Ali, Hapipah Mohd Khaledi, H. |
| author_sort | Salga, M.S. |
| collection | UM |
| description | In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is pentacoordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)ethyl] iminomethyl} phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent molecules are linked together via N-H center dot center dot center dot O and N-H center dot center dot center dot Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C-H center dot center dot center dot Cl interactions into a three-dimensional network. |
| first_indexed | 2024-03-06T05:13:58Z |
| format | Article |
| id | um.eprints-5273 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:58Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52732019-01-31T04:52:25Z http://eprints.um.edu.my/5273/ Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II) Salga, M.S. Ali, Hapipah Mohd Khaledi, H. QD Chemistry In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is pentacoordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)ethyl] iminomethyl} phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent molecules are linked together via N-H center dot center dot center dot O and N-H center dot center dot center dot Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C-H center dot center dot center dot Cl interactions into a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5273/1/Salga-2010-Dichlorido%282-%7B_2-%28pi.pdf Salga, M.S. and Ali, Hapipah Mohd and Khaledi, H. (2010) Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II). Acta Crystallographica Section E: Structure Reports Online, 66. M1131-U823. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810032563 <https://doi.org/10.1107/s1600536810032563>. http://scripts.iucr.org/cgi-bin/paper?S1600536810032563 10.1107/s1600536810032563 |
| spellingShingle | QD Chemistry Salga, M.S. Ali, Hapipah Mohd Khaledi, H. Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II) |
| title | Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II) |
| title_full | Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II) |
| title_fullStr | Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II) |
| title_full_unstemmed | Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II) |
| title_short | Dichlorido(2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}phenolate)cadmium(II) |
| title_sort | dichlorido 2 2 piperazin 4 ium 1 yl ethyl iminomethyl phenolate cadmium ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5273/1/Salga-2010-Dichlorido%282-%7B_2-%28pi.pdf |
| work_keys_str_mv | AT salgams dichlorido22piperazin4ium1ylethyliminomethylphenolatecadmiumii AT alihapipahmohd dichlorido22piperazin4ium1ylethyliminomethylphenolatecadmiumii AT khaledih dichlorido22piperazin4ium1ylethyliminomethylphenolatecadmiumii |