N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV)
The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot ce...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5280/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf |
| _version_ | 1825719067797880832 |
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| author | Lee, S.M. Lo, K.M. Ali, Hapipah Mohd |
| author_facet | Lee, S.M. Lo, K.M. Ali, Hapipah Mohd |
| author_sort | Lee, S.M. |
| collection | UM |
| description | The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. |
| first_indexed | 2024-03-06T05:13:59Z |
| format | Article |
| id | um.eprints-5280 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:59Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52802019-01-29T08:56:38Z http://eprints.um.edu.my/5280/ N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV) Lee, S.M. Lo, K.M. Ali, Hapipah Mohd QD Chemistry The environment at the Sn-IV atom in the title compound, [Sn(C6H11)(2)(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)degrees. The presence of an intramolecular O-H center dot center dot center dot N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5280/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf Lee, S.M. and Lo, K.M. and Ali, Hapipah Mohd (2010) N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66. M162-U717. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810001145 <https://doi.org/10.1107/s1600536810001145>. http://scripts.iucr.org/cgi-bin/paper?S1600536810001145 10.1107/s1600536810001145 |
| spellingShingle | QD Chemistry Lee, S.M. Lo, K.M. Ali, Hapipah Mohd N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV) |
| title | N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV) |
| title_full | N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV) |
| title_fullStr | N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV) |
| title_full_unstemmed | N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV) |
| title_short | N '-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O dicyclohexyltin(IV) |
| title_sort | n 5 bromo 2 oxidobenzylidene kappa o 3 hydroxy 2 naphthohydrazidato kappa n 2 o dicyclohexyltin iv |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5280/1/Lee-2010-N_%27-%285-Bromo-2-oxido.pdf |
| work_keys_str_mv | AT leesm n5bromo2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2odicyclohexyltiniv AT lokm n5bromo2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2odicyclohexyltiniv AT alihapipahmohd n5bromo2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2odicyclohexyltiniv |