Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV)
The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules diffe...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5301/1/Khaledi-2010-Bis%28acetato-kappa_O-.pdf |
| _version_ | 1825719071407079424 |
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| author | Khaledi, H. Abdulla, M.A. Ali, Hapipah Mohd |
| author_facet | Khaledi, H. Abdulla, M.A. Ali, Hapipah Mohd |
| author_sort | Khaledi, H. |
| collection | UM |
| description | The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15)and 60.11 (14)degrees in the two molecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2)and 41.77 (13)degrees in the two molecules. |
| first_indexed | 2024-03-06T05:14:03Z |
| format | Article |
| id | um.eprints-5301 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:03Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-53012019-01-29T09:10:29Z http://eprints.um.edu.my/5301/ Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV) Khaledi, H. Abdulla, M.A. Ali, Hapipah Mohd QD Chemistry The asymmetric unit of the title compound, [Sn(C6H5)(2)-(C2H3O2)(2)(C5H5N)], contains two crystallography independent molecules. In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. The two molecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15)and 60.11 (14)degrees in the two molecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2)and 41.77 (13)degrees in the two molecules. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5301/1/Khaledi-2010-Bis%28acetato-kappa_O-.pdf Khaledi, H. and Abdulla, M.A. and Ali, Hapipah Mohd (2010) Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV). Acta Crystallographica Section E: Structure Reports Online, 66. M351-U184. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810007014 <https://doi.org/10.1107/s1600536810007014>. http://scripts.iucr.org/cgi-bin/paper?S1600536810007014 10.1107/s1600536810007014 |
| spellingShingle | QD Chemistry Khaledi, H. Abdulla, M.A. Ali, Hapipah Mohd Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV) |
| title | Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV) |
| title_full | Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV) |
| title_fullStr | Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV) |
| title_full_unstemmed | Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV) |
| title_short | Bis(acetato-kappa O-2,O ')diphenyl(pyridine-kappa N)tin(IV) |
| title_sort | bis acetato kappa o 2 o diphenyl pyridine kappa n tin iv |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5301/1/Khaledi-2010-Bis%28acetato-kappa_O-.pdf |
| work_keys_str_mv | AT khaledih bisacetatokappao2odiphenylpyridinekappantiniv AT abdullama bisacetatokappao2odiphenylpyridinekappantiniv AT alihapipahmohd bisacetatokappao2odiphenylpyridinekappantiniv |