Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate
The metal atom of the title compound, [Zn(C13H8N3O2S)(2)]center dot C3H7NO center dot H2O, is O,N,O '- chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecu...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Online Access: | http://eprints.um.edu.my/5309/1/Halim-2010-Bis_N_%27-%282-oxo-1H-in.pdf |
| _version_ | 1796945265121296384 |
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| author | Halim, S.N.A. Ng, S.W. Ali, Hapipah Mohd |
| author_facet | Halim, S.N.A. Ng, S.W. Ali, Hapipah Mohd |
| author_sort | Halim, S.N.A. |
| collection | UM |
| description | The metal atom of the title compound, [Zn(C13H8N3O2S)(2)]center dot C3H7NO center dot H2O, is O,N,O '- chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. |
| first_indexed | 2024-03-06T05:14:04Z |
| format | Article |
| id | um.eprints-5309 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:04Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-53092019-01-29T09:09:05Z http://eprints.um.edu.my/5309/ Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate Halim, S.N.A. Ng, S.W. Ali, Hapipah Mohd QD Chemistry The metal atom of the title compound, [Zn(C13H8N3O2S)(2)]center dot C3H7NO center dot H2O, is O,N,O '- chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5309/1/Halim-2010-Bis_N_%27-%282-oxo-1H-in.pdf Halim, S.N.A. and Ng, S.W. and Ali, Hapipah Mohd (2010) Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66. M1438-U938. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810039504 <https://doi.org/10.1107/s1600536810039504>. http://scripts.iucr.org/cgi-bin/paper?S1600536810039504 10.1107/s1600536810039504 |
| spellingShingle | QD Chemistry Halim, S.N.A. Ng, S.W. Ali, Hapipah Mohd Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title | Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_full | Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_fullStr | Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_full_unstemmed | Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_short | Bis N '-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-kappa O-3,N ',O ' zinc(II) N,N-dimethylformide monosolvate monohydrate |
| title_sort | bis n 2 oxo 1h indol 3 ylidene thiophene 2 carbohydrazidato kappa o 3 n o zinc ii n n dimethylformide monosolvate monohydrate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5309/1/Halim-2010-Bis_N_%27-%282-oxo-1H-in.pdf |
| work_keys_str_mv | AT halimsna bisn2oxo1hindol3ylidenethiophene2carbohydrazidatokappao3nozinciinndimethylformidemonosolvatemonohydrate AT ngsw bisn2oxo1hindol3ylidenethiophene2carbohydrazidatokappao3nozinciinndimethylformidemonosolvatemonohydrate AT alihapipahmohd bisn2oxo1hindol3ylidenethiophene2carbohydrazidatokappao3nozinciinndimethylformidemonosolvatemonohydrate |