(1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II)
In the title compound, [Cu(C21H22N2O2)], the cyclohexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The CuII ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Online Access: | http://eprints.um.edu.my/5312/1/Gwaram-2010-%281S%2C2S%29-2-%281-%7B_2-%282-.pdf |
| _version_ | 1825719073553514496 |
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| author | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
| author_facet | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. |
| author_sort | Gwaram, N.S. |
| collection | UM |
| description | In the title compound, [Cu(C21H22N2O2)], the cyclohexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The CuII ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, intermolecular C-H...O interactions are present and stabilize the structure.
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| first_indexed | 2024-03-06T05:14:05Z |
| format | Article |
| id | um.eprints-5312 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:05Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-53122019-01-29T09:14:09Z http://eprints.um.edu.my/5312/ (1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II) Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. QD Chemistry In the title compound, [Cu(C21H22N2O2)], the cyclohexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The CuII ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, intermolecular C-H...O interactions are present and stabilize the structure. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5312/1/Gwaram-2010-%281S%2C2S%29-2-%281-%7B_2-%282-.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. (2010) (1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II). Acta Crystallographica Section E: Structure Reports Online, 66. M813-U892. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810022889 <https://doi.org/10.1107/s1600536810022889>. http://scripts.iucr.org/cgi-bin/paper?S1600536810022889 10.1107/s1600536810022889 |
| spellingShingle | QD Chemistry Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. (1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II) |
| title | (1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II) |
| title_full | (1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II) |
| title_fullStr | (1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II) |
| title_full_unstemmed | (1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II) |
| title_short | (1S,2S)-2-(1-{ 2-(2-Oxidobenzylideneamino)cyclohexyl imino}-ethyl)pheno lato-kappa O-4,N,N ',O ' copper(II) |
| title_sort | 1s 2s 2 1 2 2 oxidobenzylideneamino cyclohexyl imino ethyl pheno lato kappa o 4 n n o copper ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5312/1/Gwaram-2010-%281S%2C2S%29-2-%281-%7B_2-%282-.pdf |
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