2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid
In the title compound, C(22)H(28)O(3)S, the dihedral angle between the two aromatic rings is 80.56 (6)degrees. The hydroxy group is shielded by the two sterically hindered tert-butyl groups and therefore is not involved in any hydrogen bonding. The C-O-H fragment is coplanar with the aromatic ring,...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5325/1/Alhadi-2010-2-_%283%2C5-Di-tert-buty.pdf |
| _version_ | 1825719076063805440 |
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| author | Alhadi, A.A. Olmstead, M.M. Ali, Hapipah Mohd Khaledi, H. |
| author_facet | Alhadi, A.A. Olmstead, M.M. Ali, Hapipah Mohd Khaledi, H. |
| author_sort | Alhadi, A.A. |
| collection | UM |
| description | In the title compound, C(22)H(28)O(3)S, the dihedral angle between the two aromatic rings is 80.56 (6)degrees. The hydroxy group is shielded by the two sterically hindered tert-butyl groups and therefore is not involved in any hydrogen bonding. The C-O-H fragment is coplanar with the aromatic ring, the dihedral angle between them being 7(5)degrees. In the crystal structure, pairs of molecules are hydrogen bonded across crystallographic centers of symmetry. |
| first_indexed | 2024-03-06T05:14:07Z |
| format | Article |
| id | um.eprints-5325 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:07Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-53252019-01-29T09:15:15Z http://eprints.um.edu.my/5325/ 2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid Alhadi, A.A. Olmstead, M.M. Ali, Hapipah Mohd Khaledi, H. QD Chemistry In the title compound, C(22)H(28)O(3)S, the dihedral angle between the two aromatic rings is 80.56 (6)degrees. The hydroxy group is shielded by the two sterically hindered tert-butyl groups and therefore is not involved in any hydrogen bonding. The C-O-H fragment is coplanar with the aromatic ring, the dihedral angle between them being 7(5)degrees. In the crystal structure, pairs of molecules are hydrogen bonded across crystallographic centers of symmetry. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5325/1/Alhadi-2010-2-_%283%2C5-Di-tert-buty.pdf Alhadi, A.A. and Olmstead, M.M. and Ali, Hapipah Mohd and Khaledi, H. (2010) 2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid. Acta Crystallographica Section E: Structure Reports Online, 66. O1787-U436. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810023731 <https://doi.org/10.1107/s1600536810023731>. http://scripts.iucr.org/cgi-bin/paper?S1600536810023731 10.1107/s1600536810023731 |
| spellingShingle | QD Chemistry Alhadi, A.A. Olmstead, M.M. Ali, Hapipah Mohd Khaledi, H. 2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid |
| title | 2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid |
| title_full | 2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid |
| title_fullStr | 2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid |
| title_full_unstemmed | 2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid |
| title_short | 2- (3,5-Di-tert-butyl-4-hydroxybenzyl) sulfanyl benzoic acid |
| title_sort | 2 3 5 di tert butyl 4 hydroxybenzyl sulfanyl benzoic acid |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5325/1/Alhadi-2010-2-_%283%2C5-Di-tert-buty.pdf |
| work_keys_str_mv | AT alhadiaa 235ditertbutyl4hydroxybenzylsulfanylbenzoicacid AT olmsteadmm 235ditertbutyl4hydroxybenzylsulfanylbenzoicacid AT alihapipahmohd 235ditertbutyl4hydroxybenzylsulfanylbenzoicacid AT khaledih 235ditertbutyl4hydroxybenzylsulfanylbenzoicacid |