Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]
The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted squarepyramidal geom...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf |
| _version_ | 1796945268770340864 |
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| author | Ahaker, S. Mohd Ali, H. Khaledi, H. |
| author_facet | Ahaker, S. Mohd Ali, H. Khaledi, H. |
| author_sort | Ahaker, S. |
| collection | UM |
| description | The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric
dinuclear cadmium(II) complex in which each two
metal ions are linked by a pair of thiocyanate N:S-bridges. Two
2-methylbenzimidazole N-atom donors and one terminal
thiocyanate N atom complete a highly distorted squarepyramidal
geometry around the Cd atom. In the crystal
structure, two N—H� � �S hydrogen-bonding interactions
occur, resulting in a three-dimensional polymeric structure.
The apical 2-methylbenzimidazole ring and its symmetryrelated
counterpart are arranged in an antiparallel manner
with a centroid–centroid separation of 3.6050 (14) A ° , indicative
of a �–� interaction. |
| first_indexed | 2024-03-06T05:14:07Z |
| format | Article |
| id | um.eprints-5327 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:07Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | um.eprints-53272013-04-01T04:33:41Z http://eprints.um.edu.my/5327/ Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] Ahaker, S. Mohd Ali, H. Khaledi, H. QD Chemistry The title compound, [Cd2(NCS)4(C8H8N2)4], is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted squarepyramidal geometry around the Cd atom. In the crystal structure, two N—H� � �S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetryrelated counterpart are arranged in an antiparallel manner with a centroid–centroid separation of 3.6050 (14) A ° , indicative of a �–� interaction. 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf Ahaker, S. and Mohd Ali, H. and Khaledi, H. (2010) Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)]. Acta Crystallographica Section E: Structure Reports Online, 66 (11). m1464-m1464. ISSN 1600-5368, http://journals.iucr.org/e/issues/2010/11/00/pk2278/pk2278.pdf |
| spellingShingle | QD Chemistry Ahaker, S. Mohd Ali, H. Khaledi, H. Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
| title | Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
| title_full | Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
| title_fullStr | Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
| title_full_unstemmed | Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
| title_short | Di--thiocyanato-2N: S; 2S: N-bis [bis (2-methyl-1H-benzimidazole-N3)(thiocyanato-N) cadmium (II)] |
| title_sort | di thiocyanato 2n s 2s n bis bis 2 methyl 1h benzimidazole n3 thiocyanato n cadmium ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5327/1/Ahaker-2010-Di--thiocyanato-2N_.pdf |
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