Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O '
The title compound, [Sn(C6H5)(3)(C17H25O3S)](n), comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The Sn-IV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-buty...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5354/1/Lee-2009-catena-Poly_tripheny.pdf |
| _version_ | 1796945273518292992 |
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| author | Lee, S.M. Robinson, W.T. Ali, Hapipah Mohd Lo, K.M. |
| author_facet | Lee, S.M. Robinson, W.T. Ali, Hapipah Mohd Lo, K.M. |
| author_sort | Lee, S.M. |
| collection | UM |
| description | The title compound, [Sn(C6H5)(3)(C17H25O3S)](n), comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The Sn-IV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding interactions involving the hydroxyl substituents. |
| first_indexed | 2024-03-06T05:14:12Z |
| format | Article |
| id | um.eprints-5354 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:12Z |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-53542019-01-29T08:39:27Z http://eprints.um.edu.my/5354/ Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O ' Lee, S.M. Robinson, W.T. Ali, Hapipah Mohd Lo, K.M. QD Chemistry The title compound, [Sn(C6H5)(3)(C17H25O3S)](n), comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The Sn-IV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding interactions involving the hydroxyl substituents. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5354/1/Lee-2009-catena-Poly_tripheny.pdf Lee, S.M. and Robinson, W.T. and Ali, Hapipah Mohd and Lo, K.M. (2009) Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O '. Acta Crystallographica Section E: Structure Reports Online, 65. M808-U1140. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809023150 <https://doi.org/10.1107/s1600536809023150>. 10.1107/s1600536809023150 |
| spellingShingle | QD Chemistry Lee, S.M. Robinson, W.T. Ali, Hapipah Mohd Lo, K.M. Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O ' |
| title | Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O ' |
| title_full | Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O ' |
| title_fullStr | Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O ' |
| title_full_unstemmed | Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O ' |
| title_short | Catena-Poly triphenyltin(IV) -mu-2- (3,5-di-tert-butyl-4-hydroxybenzyl) sulfanyl acetato-kappa O-2:O ' |
| title_sort | catena poly triphenyltin iv mu 2 3 5 di tert butyl 4 hydroxybenzyl sulfanyl acetato kappa o 2 o |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5354/1/Lee-2009-catena-Poly_tripheny.pdf |
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