Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1)
In the title compound, (C7H11N2)(2)[SnBr4(C6H4Cl)(2)]center dot-C6H4BrCl, the Sn-IV atom in the tetrabromidobis(4-chlorophenyl)stannate(IV) anion lies on a centre of inversion. The distances between the 4-(dimethylamino)pyridinium N atom and the Br atoms of the anion are 3.450 (2) and 3.452 (2) angs...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5355/1/Lee-2009-Bis_4-%28dimethylamino.pdf |
| _version_ | 1796945273719619584 |
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| author | Lee, S.M. Robinson, W.T. Ali, Hapipah Mohd Lo, K.M. |
| author_facet | Lee, S.M. Robinson, W.T. Ali, Hapipah Mohd Lo, K.M. |
| author_sort | Lee, S.M. |
| collection | UM |
| description | In the title compound, (C7H11N2)(2)[SnBr4(C6H4Cl)(2)]center dot-C6H4BrCl, the Sn-IV atom in the tetrabromidobis(4-chlorophenyl)stannate(IV) anion lies on a centre of inversion. The distances between the 4-(dimethylamino)pyridinium N atom and the Br atoms of the anion are 3.450 (2) and 3.452 (2) angstrom, suggesting weak hydrogen bonding. The 4-bromochlorobenzene solvent molecule, which is a bromination by-product from the reaction, is disordered about a twofold rotation axis with approximately equal occupancy. |
| first_indexed | 2024-03-06T05:14:12Z |
| format | Article |
| id | um.eprints-5355 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:12Z |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-53552019-01-29T08:52:16Z http://eprints.um.edu.my/5355/ Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1) Lee, S.M. Robinson, W.T. Ali, Hapipah Mohd Lo, K.M. QD Chemistry In the title compound, (C7H11N2)(2)[SnBr4(C6H4Cl)(2)]center dot-C6H4BrCl, the Sn-IV atom in the tetrabromidobis(4-chlorophenyl)stannate(IV) anion lies on a centre of inversion. The distances between the 4-(dimethylamino)pyridinium N atom and the Br atoms of the anion are 3.450 (2) and 3.452 (2) angstrom, suggesting weak hydrogen bonding. The 4-bromochlorobenzene solvent molecule, which is a bromination by-product from the reaction, is disordered about a twofold rotation axis with approximately equal occupancy. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5355/1/Lee-2009-Bis_4-%28dimethylamino.pdf Lee, S.M. and Robinson, W.T. and Ali, Hapipah Mohd and Lo, K.M. (2009) Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1). Acta Crystallographica Section E: Structure Reports Online, 65. N1039-U291. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809030232 <https://doi.org/10.1107/s1600536809030232>. http://journals.iucr.org/e/issues/2009/09/00/hg2523/hg2523.pdf 10.1107/s1600536809030232 |
| spellingShingle | QD Chemistry Lee, S.M. Robinson, W.T. Ali, Hapipah Mohd Lo, K.M. Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1) |
| title | Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1) |
| title_full | Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1) |
| title_fullStr | Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1) |
| title_full_unstemmed | Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1) |
| title_short | Bis 4-(dimethylamino)pyridinium tetrabromidobis(4-chlorophenyl)stannate(IV)-4-bromochlorobenzene (1/1) |
| title_sort | bis 4 dimethylamino pyridinium tetrabromidobis 4 chlorophenyl stannate iv 4 bromochlorobenzene 1 1 |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5355/1/Lee-2009-Bis_4-%28dimethylamino.pdf |
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