Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II)
The central Cd-II atom in the trinuclear title compound, [Cd-3(C14H19N2O3)(2)(CH3COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedral geometry....
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| Format: | Article |
| Jezik: | English |
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International Union of Crystallography
2009
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| Online dostop: | http://eprints.um.edu.my/5384/1/Lair-2009-Tetra-mu%282%29-acetato-.pdf |
| _version_ | 1825719086822195200 |
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| author | Lair, N.M. Ng, S.W. Ali, Hapipah Mohd |
| author_facet | Lair, N.M. Ng, S.W. Ali, Hapipah Mohd |
| author_sort | Lair, N.M. |
| collection | UM |
| description | The central Cd-II atom in the trinuclear title compound, [Cd-3(C14H19N2O3)(2)(CH3COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedral geometry. Two of the acetate groups function in a mu(2)-bridging mode, while the other two each chelate to the terminal Cd-II atom and simultaneously bind to the central metal atom in a kappa(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation. |
| first_indexed | 2024-03-06T05:14:17Z |
| format | Article |
| id | um.eprints-5384 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:17Z |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-53842019-01-29T08:36:12Z http://eprints.um.edu.my/5384/ Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II) Lair, N.M. Ng, S.W. Ali, Hapipah Mohd QD Chemistry The central Cd-II atom in the trinuclear title compound, [Cd-3(C14H19N2O3)(2)(CH3COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedral geometry. Two of the acetate groups function in a mu(2)-bridging mode, while the other two each chelate to the terminal Cd-II atom and simultaneously bind to the central metal atom in a kappa(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5384/1/Lair-2009-Tetra-mu%282%29-acetato-.pdf Lair, N.M. and Ng, S.W. and Ali, Hapipah Mohd (2009) Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II). Acta Crystallographica Section E: Structure Reports Online, 65. M1011-U1703. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809029171 <https://doi.org/10.1107/s1600536809029171>. http://scripts.iucr.org/cgi-bin/paper?S1600536809029171 10.1107/s1600536809029171 |
| spellingShingle | QD Chemistry Lair, N.M. Ng, S.W. Ali, Hapipah Mohd Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II) |
| title | Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II) |
| title_full | Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II) |
| title_fullStr | Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II) |
| title_full_unstemmed | Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II) |
| title_short | Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II) |
| title_sort | tetra mu 2 acetato bis mu 2 5 methoxy 2 2 morpholinoethyl iminiometh yl phenolato tricadmium ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5384/1/Lair-2009-Tetra-mu%282%29-acetato-.pdf |
| work_keys_str_mv | AT lairnm tetramu2acetatobismu25methoxy22morpholinoethyliminiomethylphenolatotricadmiumii AT ngsw tetramu2acetatobismu25methoxy22morpholinoethyliminiomethylphenolatotricadmiumii AT alihapipahmohd tetramu2acetatobismu25methoxy22morpholinoethyliminiomethylphenolatotricadmiumii |