trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II)
The Ni atom in the centrosymmetric title compound, [Ni(C10H9N4S)2], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH2 frament is planar. Adjacent molecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acc...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5439/1/Rizal-2008-trans-Bis%281H-indole-.pdf |
| _version_ | 1796945288758296576 |
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| author | Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng |
| author_facet | Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng |
| author_sort | Rizal, Mohd Razali |
| collection | UM |
| description | The Ni atom in the centrosymmetric title compound, [Ni(C10H9N4S)2], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH2 frament is planar. Adjacent molecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acceptor) site of an adjacent molecule, forming a layer motif. |
| first_indexed | 2024-03-06T05:14:25Z |
| format | Article |
| id | um.eprints-5439 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:25Z |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-54392020-12-11T07:33:56Z http://eprints.um.edu.my/5439/ trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II) Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng QD Chemistry The Ni atom in the centrosymmetric title compound, [Ni(C10H9N4S)2], is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH2 frament is planar. Adjacent molecules are linked by hydrogen bonds between the indolyl –NH (donor) site and the double-bond =N– (acceptor) site of an adjacent molecule, forming a layer motif. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5439/1/Rizal-2008-trans-Bis%281H-indole-.pdf Rizal, Mohd Razali and Ali, Hapipah Mohd and Ng, Seik Weng (2008) trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II). Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 6). m824. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536808014293 <https://doi.org/10.1107/s1600536808014293>. https://doi.org/10.1107/S1600536808014293 doi:10.1107/s1600536808014293 |
| spellingShingle | QD Chemistry Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II) |
| title | trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II) |
| title_full | trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II) |
| title_fullStr | trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II) |
| title_full_unstemmed | trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II) |
| title_short | trans-Bis(1H-indole-3-carbaldehyde thiosemicarbazonato-κ2 N 1,S)nickel(II) |
| title_sort | trans bis 1h indole 3 carbaldehyde thio semicarbazonato κ2 n 1 s nickel ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5439/1/Rizal-2008-trans-Bis%281H-indole-.pdf |
| work_keys_str_mv | AT rizalmohdrazali transbis1hindole3carbaldehydethiosemicarbazonatok2n1snickelii AT alihapipahmohd transbis1hindole3carbaldehydethiosemicarbazonatok2n1snickelii AT ngseikweng transbis1hindole3carbaldehydethiosemicarbazonatok2n1snickelii |