Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate
The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C19H15N6S)2]·2C2H6OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites interact with dimethyl sulfoxide molecu...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008
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| Online Access: | http://eprints.um.edu.my/5440/1/Rizal-2008-Bis_1%2C5-bis%281H-indol.pdf |
| _version_ | 1825719095795908608 |
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| author | Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng |
| author_facet | Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng |
| author_sort | Rizal, Mohd Razali |
| collection | UM |
| description | The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C19H15N6S)2]·2C2H6OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites interact with dimethyl sulfoxide molecules to furnish a layer motif. |
| first_indexed | 2024-03-06T05:14:25Z |
| format | Article |
| id | um.eprints-5440 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:25Z |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-54402020-12-11T07:24:16Z http://eprints.um.edu.my/5440/ Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng QD Chemistry The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C19H15N6S)2]·2C2H6OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites interact with dimethyl sulfoxide molecules to furnish a layer motif. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5440/1/Rizal-2008-Bis_1%2C5-bis%281H-indol.pdf Rizal, Mohd Razali and Ali, Hapipah Mohd and Ng, Seik Weng (2008) Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate. Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 6). m755. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536808011975 <https://doi.org/10.1107/s1600536808011975>. https://doi.org/10.1107/S1600536808011975 doi:10.1107/s1600536808011975 |
| spellingShingle | QD Chemistry Rizal, Mohd Razali Ali, Hapipah Mohd Ng, Seik Weng Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate |
| title | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_full | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_fullStr | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_full_unstemmed | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_short | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ2 N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_sort | bis 1 5 bis 1h indol 3 ylmethyl ene thio carbazonato κ2 n s nickel ii dimethyl sulfoxide disolvate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5440/1/Rizal-2008-Bis_1%2C5-bis%281H-indol.pdf |
| work_keys_str_mv | AT rizalmohdrazali bis15bis1hindol3ylmethylenethiocarbazonatok2nsnickeliidimethylsulfoxidedisolvate AT alihapipahmohd bis15bis1hindol3ylmethylenethiocarbazonatok2nsnickeliidimethylsulfoxidedisolvate AT ngseikweng bis15bis1hindol3ylmethylenethiocarbazonatok2nsnickeliidimethylsulfoxidedisolvate |