Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate
In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]center dot 2C(3)H(7)NO, the Ni atom (site symmetry (1) over bar) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)degrees....
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5460/1/Khaledi-2008-Bis_benzyl_N_%27-%281H-i.pdf |
| _version_ | 1825719098768621568 |
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| author | Khaledi, H. Ng, S.W. Ali, Hapipah Mohd |
| author_facet | Khaledi, H. Ng, S.W. Ali, Hapipah Mohd |
| author_sort | Khaledi, H. |
| collection | UM |
| description | In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]center dot 2C(3)H(7)NO, the Ni atom (site symmetry (1) over bar) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)degrees. In the crystal structure, an N-H center dot center dot center dot O hydrogen bond links the complex to the dimethylformamide solvent molecule. |
| first_indexed | 2024-03-06T05:14:28Z |
| format | Article |
| id | um.eprints-5460 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:28Z |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-54602019-01-29T08:17:58Z http://eprints.um.edu.my/5460/ Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate Khaledi, H. Ng, S.W. Ali, Hapipah Mohd QD Chemistry In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]center dot 2C(3)H(7)NO, the Ni atom (site symmetry (1) over bar) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)degrees. In the crystal structure, an N-H center dot center dot center dot O hydrogen bond links the complex to the dimethylformamide solvent molecule. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5460/1/Khaledi-2008-Bis_benzyl_N_%27-%281H-i.pdf Khaledi, H. and Ng, S.W. and Ali, Hapipah Mohd (2008) Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate. Acta Crystallographica Section E: Structure Reports Online, 64. M1615-U1249. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536808038580 <https://doi.org/10.1107/s1600536808038580>. http://scripts.iucr.org/cgi-bin/paper?S1600536808038580 10.1107/s1600536808038580 |
| spellingShingle | QD Chemistry Khaledi, H. Ng, S.W. Ali, Hapipah Mohd Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate |
| title | Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate |
| title_full | Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate |
| title_fullStr | Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate |
| title_full_unstemmed | Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate |
| title_short | Bis benzyl N '-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-kappa(2)N ',S nickel(II) N,N-dimethylformamide disolvate |
| title_sort | bis benzyl n 1h indol 3 ylmethylene hydrazinecarbodithioato kappa 2 n s nickel ii n n dimethylformamide disolvate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5460/1/Khaledi-2008-Bis_benzyl_N_%27-%281H-i.pdf |
| work_keys_str_mv | AT khaledih bisbenzyln1hindol3ylmethylenehydrazinecarbodithioatokappa2nsnickeliinndimethylformamidedisolvate AT ngsw bisbenzyln1hindol3ylmethylenehydrazinecarbodithioatokappa2nsnickeliinndimethylformamidedisolvate AT alihapipahmohd bisbenzyln1hindol3ylmethylenehydrazinecarbodithioatokappa2nsnickeliinndimethylformamidedisolvate |