Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate
The Ni atom in the title compound, [Ni(C17H15N2O)2]·2C3H7NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolate ligand in a square-planar coordination environment. The molecule is linked to a solvent molecule by an...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008
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| Online Access: | http://eprints.um.edu.my/5467/1/Ali-2008-Bis%7B2-_2-%281H-indol-3.pdf |
| _version_ | 1796945293369933824 |
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| author | Ali, Hapipah Mohd Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd Razali Ng, Seik Weng |
| author_facet | Ali, Hapipah Mohd Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd Razali Ng, Seik Weng |
| author_sort | Ali, Hapipah Mohd |
| collection | UM |
| description | The Ni atom in the title compound, [Ni(C17H15N2O)2]·2C3H7NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolate ligand in a square-planar coordination environment. The molecule is linked to a solvent molecule by an indole–dimethylformamide N—H⋯O hydrogen bond. |
| first_indexed | 2024-03-06T05:14:29Z |
| format | Article |
| id | um.eprints-5467 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:29Z |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-54672020-09-01T08:21:43Z http://eprints.um.edu.my/5467/ Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate Ali, Hapipah Mohd Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd Razali Ng, Seik Weng QD Chemistry The Ni atom in the title compound, [Ni(C17H15N2O)2]·2C3H7NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolate ligand in a square-planar coordination environment. The molecule is linked to a solvent molecule by an indole–dimethylformamide N—H⋯O hydrogen bond. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5467/1/Ali-2008-Bis%7B2-_2-%281H-indol-3.pdf Ali, Hapipah Mohd and Mohamed Mustafa, Mohamed Ibrahim and Rizal, Mohd Razali and Ng, Seik Weng (2008) Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate. Acta Crystallographica Section E: Structure Reports Online, 64. M787-U514. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536808012968 <https://doi.org/10.1107/s1600536808012968>. https://doi.org/10.1107/S1600536808012968 doi:10.1107/s1600536808012968 |
| spellingShingle | QD Chemistry Ali, Hapipah Mohd Mohamed Mustafa, Mohamed Ibrahim Rizal, Mohd Razali Ng, Seik Weng Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate |
| title | Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate |
| title_full | Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate |
| title_fullStr | Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate |
| title_full_unstemmed | Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate |
| title_short | Bis{2-[2-(1H-indol-3-yl)ethyliminomethyl]phenolato-κ2 N,O}nickel(II) N,N-dimethylformamide disolvate |
| title_sort | bis 2 2 1h indol 3 yl ethyl imino meth yl phenolato κ2 n o nickel ii n n dimethyl formamide disolvate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5467/1/Ali-2008-Bis%7B2-_2-%281H-indol-3.pdf |
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