Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate
The Ni atom in the title compound, [Ni(C19H14ClN4O)(2)]center dot 2C(2)H(6)OS, which lies on a centre of inversion, is N, O-chelated by the two monoanionic ligands in a square-planar geometry. The asymmetric unit also contains a dimethyl sulfoxide solvent molecule. The donor amino sites of the metal...
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| Format: | Article |
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International Union of Crystallography
2007
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| _version_ | 1825719106114945024 |
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| author | Ali, Hapipah Mohd Ng, S.W. Rizal, M.R. Nazzatush, J. |
| author_facet | Ali, Hapipah Mohd Ng, S.W. Rizal, M.R. Nazzatush, J. |
| author_sort | Ali, Hapipah Mohd |
| collection | UM |
| description | The Ni atom in the title compound, [Ni(C19H14ClN4O)(2)]center dot 2C(2)H(6)OS, which lies on a centre of inversion, is N, O-chelated by the two monoanionic ligands in a square-planar geometry. The asymmetric unit also contains a dimethyl sulfoxide solvent molecule. The donor amino sites of the metal-bearing molecule interact with the solvent molecules to furnish a hydrogen-bonded layer structure. |
| first_indexed | 2024-03-06T05:14:35Z |
| format | Article |
| id | um.eprints-5510 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:14:35Z |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-55102019-01-31T01:21:55Z http://eprints.um.edu.my/5510/ Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate Ali, Hapipah Mohd Ng, S.W. Rizal, M.R. Nazzatush, J. QD Chemistry The Ni atom in the title compound, [Ni(C19H14ClN4O)(2)]center dot 2C(2)H(6)OS, which lies on a centre of inversion, is N, O-chelated by the two monoanionic ligands in a square-planar geometry. The asymmetric unit also contains a dimethyl sulfoxide solvent molecule. The donor amino sites of the metal-bearing molecule interact with the solvent molecules to furnish a hydrogen-bonded layer structure. International Union of Crystallography 2007 Article PeerReviewed Ali, Hapipah Mohd and Ng, S.W. and Rizal, M.R. and Nazzatush, J. (2007) Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate. Acta Crystallographica Section E: Structure Reports Online, 63. M3033-U1568. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536807056966 <https://doi.org/10.1107/s1600536807056966>. http://scripts.iucr.org/cgi-bin/paper?S1600536807056966 10.1107/s1600536807056966 |
| spellingShingle | QD Chemistry Ali, Hapipah Mohd Ng, S.W. Rizal, M.R. Nazzatush, J. Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate |
| title | Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate |
| title_full | Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate |
| title_fullStr | Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate |
| title_full_unstemmed | Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate |
| title_short | Bis{2 '- (5-chloro-1H-3-indolyl)methylene 2-(1H-3-indolyl)acetohydrazido-kappa N-2,O}nickel(II) dimethyl sulfoxide disolvate |
| title_sort | bis 2 5 chloro 1h 3 indolyl methylene 2 1h 3 indolyl acetohydrazido kappa n 2 o nickel ii dimethyl sulfoxide disolvate |
| topic | QD Chemistry |
| work_keys_str_mv | AT alihapipahmohd bis25chloro1h3indolylmethylene21h3indolylacetohydrazidokappan2onickeliidimethylsulfoxidedisolvate AT ngsw bis25chloro1h3indolylmethylene21h3indolylacetohydrazidokappan2onickeliidimethylsulfoxidedisolvate AT rizalmr bis25chloro1h3indolylmethylene21h3indolylacetohydrazidokappan2onickeliidimethylsulfoxidedisolvate AT nazzatushj bis25chloro1h3indolylmethylene21h3indolylacetohydrazidokappan2onickeliidimethylsulfoxidedisolvate |