2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide
The title compound, C15H11Cl2N 3O2S, has a similar structure and similar structural dimensions to the unsubstituted N-(N-benzoylhydrazinocarbothioyl)benzamide. However, the presence of Cl atoms at the para and ortho positions in the benzamide and benzoyl groups, respectively, caused the dihedral ang...
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| Format: | Article |
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International Union of Crystallography
2004
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| _version_ | 1796945316170170368 |
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| author | Ali, Hapipah Mohd Yamin, B.M. Sahali Mardi, A. Khamis, N.A. Sukeri Yusof, M. |
| author_facet | Ali, Hapipah Mohd Yamin, B.M. Sahali Mardi, A. Khamis, N.A. Sukeri Yusof, M. |
| author_sort | Ali, Hapipah Mohd |
| collection | UM |
| description | The title compound, C15H11Cl2N 3O2S, has a similar structure and similar structural dimensions to the unsubstituted N-(N-benzoylhydrazinocarbothioyl)benzamide. However, the presence of Cl atoms at the para and ortho positions in the benzamide and benzoyl groups, respectively, caused the dihedral angle between these groups to increase from 16.42 (14)° in the unsubstituted compound to 74.96 (8)°. The molecule is stabilized by intermolecular C-H⋯O and N-H⋯S interactions, forming polymeric chains parallel to the c axis. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| first_indexed | 2024-03-06T05:14:50Z |
| format | Article |
| id | um.eprints-5622 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:14:50Z |
| publishDate | 2004 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-56222019-01-31T06:43:20Z http://eprints.um.edu.my/5622/ 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide Ali, Hapipah Mohd Yamin, B.M. Sahali Mardi, A. Khamis, N.A. Sukeri Yusof, M. QD Chemistry The title compound, C15H11Cl2N 3O2S, has a similar structure and similar structural dimensions to the unsubstituted N-(N-benzoylhydrazinocarbothioyl)benzamide. However, the presence of Cl atoms at the para and ortho positions in the benzamide and benzoyl groups, respectively, caused the dihedral angle between these groups to increase from 16.42 (14)° in the unsubstituted compound to 74.96 (8)°. The molecule is stabilized by intermolecular C-H⋯O and N-H⋯S interactions, forming polymeric chains parallel to the c axis. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved. International Union of Crystallography 2004 Article PeerReviewed Ali, Hapipah Mohd and Yamin, B.M. and Sahali Mardi, A. and Khamis, N.A. and Sukeri Yusof, M. (2004) 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide. Acta Crystallographica Section E: Structure Reports Online, 60 (9). o1656-o1658. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536804020525 <https://doi.org/10.1107/S1600536804020525>. http://www.scopus.com/inward/record.url?eid=2-s2.0-18444389507&partnerID=40&md5=fb9bac2469edf975508d01bdb4e4c753 10.1107/S1600536804020525 |
| spellingShingle | QD Chemistry Ali, Hapipah Mohd Yamin, B.M. Sahali Mardi, A. Khamis, N.A. Sukeri Yusof, M. 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide |
| title | 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide |
| title_full | 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide |
| title_fullStr | 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide |
| title_full_unstemmed | 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide |
| title_short | 2-Chloro-N-[N-(4-chlorobenzoyl)hydrazinocarbothioyl]benzamide |
| title_sort | 2 chloro n n 4 chlorobenzoyl hydrazinocarbothioyl benzamide |
| topic | QD Chemistry |
| work_keys_str_mv | AT alihapipahmohd 2chloronn4chlorobenzoylhydrazinocarbothioylbenzamide AT yaminbm 2chloronn4chlorobenzoylhydrazinocarbothioylbenzamide AT sahalimardia 2chloronn4chlorobenzoylhydrazinocarbothioylbenzamide AT khamisna 2chloronn4chlorobenzoylhydrazinocarbothioylbenzamide AT sukeriyusofm 2chloronn4chlorobenzoylhydrazinocarbothioylbenzamide |