{4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate
The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the tw...
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| Format: | Article |
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International Union of Crystallography
2004
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| _version_ | 1825719124066566144 |
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| author | Ali, Hapipah Mohd Yamin, B.M. Basirun, Wan Jefrey Khamis, N.A. |
| author_facet | Ali, Hapipah Mohd Yamin, B.M. Basirun, Wan Jefrey Khamis, N.A. |
| author_sort | Ali, Hapipah Mohd |
| collection | UM |
| description | The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands. © 2004 International Union of Crystallography Prinled in Great Britain - all rights reserved. |
| first_indexed | 2024-03-06T05:14:52Z |
| format | Article |
| id | um.eprints-5635 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:14:52Z |
| publishDate | 2004 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-56352019-01-31T06:42:01Z http://eprints.um.edu.my/5635/ {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate Ali, Hapipah Mohd Yamin, B.M. Basirun, Wan Jefrey Khamis, N.A. QD Chemistry The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands. © 2004 International Union of Crystallography Prinled in Great Britain - all rights reserved. International Union of Crystallography 2004 Article PeerReviewed Ali, Hapipah Mohd and Yamin, B.M. and Basirun, Wan Jefrey and Khamis, N.A. (2004) {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate. Acta Crystallographica Section E: Structure Reports Online, 60 (9). m1351-m1352. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536804020756 <https://doi.org/10.1107/S1600536804020756>. http://www.scopus.com/inward/record.url?eid=2-s2.0-18444415795&partnerID=40&md5=0e726f4566e1d1bfe645759e76c12b9d 10.1107/S1600536804020756 |
| spellingShingle | QD Chemistry Ali, Hapipah Mohd Yamin, B.M. Basirun, Wan Jefrey Khamis, N.A. {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate |
| title | {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate |
| title_full | {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate |
| title_fullStr | {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate |
| title_full_unstemmed | {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate |
| title_short | {4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate |
| title_sort | 4 chloro 2 1 5 chloro 2 oxidophenyl ethylidene κ3o n2 o benzhydrazido tris pyridine κn nickel ii pyridine solvate |
| topic | QD Chemistry |
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