(2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV)
The Schiff base ligand in the title compound, Sn(C4H 9)2(C11H12ClNO4), chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin C - Sn - C = 130.3 (1)°. The hydr-oxy groups engage in O - H�O...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Online Access: | http://eprints.um.edu.my/6838/1/2%2C2%E2%80%B2-Diethoxy-4%2C4%E2%80%B2-%5B%28E%2C_E%29-hydrazinediyl-_idenebis%28methanylylidene%29%5Ddiphenol.pdf |
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| author | Reisi, R. Misran, Misni Lo, K.M. Ng, S.W. |
| author_facet | Reisi, R. Misran, Misni Lo, K.M. Ng, S.W. |
| author_sort | Reisi, R. |
| collection | UM |
| description | The Schiff base ligand in the title compound, Sn(C4H 9)2(C11H12ClNO4), chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin C - Sn - C = 130.3 (1)°. The hydr-oxy groups engage in O - H�O hydrogen bonding with the O atoms of adjacent mol-ecules, generating a chain running along the c axis. |
| first_indexed | 2024-03-06T05:17:17Z |
| format | Article |
| id | um.eprints-6838 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:17:17Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-68382019-01-31T06:31:49Z http://eprints.um.edu.my/6838/ (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) Reisi, R. Misran, Misni Lo, K.M. Ng, S.W. QD Chemistry The Schiff base ligand in the title compound, Sn(C4H 9)2(C11H12ClNO4), chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C2SnNO2 trigonal-bipyramidal geometry at tin C - Sn - C = 130.3 (1)°. The hydr-oxy groups engage in O - H�O hydrogen bonding with the O atoms of adjacent mol-ecules, generating a chain running along the c axis. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/6838/1/2%2C2%E2%80%B2-Diethoxy-4%2C4%E2%80%B2-%5B%28E%2C_E%29-hydrazinediyl-_idenebis%28methanylylidene%29%5Ddiphenol.pdf Reisi, R. and Misran, Misni and Lo, K.M. and Ng, S.W. (2010) (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (4). m482. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536810011384 <https://doi.org/10.1107/S1600536810011384>. 10.1107/S1600536810011384 |
| spellingShingle | QD Chemistry Reisi, R. Misran, Misni Lo, K.M. Ng, S.W. (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
| title | (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
| title_full | (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
| title_fullStr | (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
| title_full_unstemmed | (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
| title_short | (2-1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-ylimino-meth-yl-4-chloro-phenolato-kap paN,O,O')dibutyl-tin(IV) |
| title_sort | 2 1 1 bis hydroxy meth yl 2 oxidoeth ylimino meth yl 4 chloro phenolato kap pan o o dibutyl tin iv |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/6838/1/2%2C2%E2%80%B2-Diethoxy-4%2C4%E2%80%B2-%5B%28E%2C_E%29-hydrazinediyl-_idenebis%28methanylylidene%29%5Ddiphenol.pdf |
| work_keys_str_mv | AT reisir 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatokappanoodibutyltiniv AT misranmisni 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatokappanoodibutyltiniv AT lokm 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatokappanoodibutyltiniv AT ngsw 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatokappanoodibutyltiniv |