Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV)
In the centrosymmetric tetranuclear title compound, [Sn4(C4H9)8(C7H5O3)4O2], one of the two independent Sn atoms is five-coordinate in a cis-C2SnO3 trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) interaction [Sn⋯O = 2.862 (1) Å]. The...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008
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| Online Access: | http://eprints.um.edu.my/6850/1/Octa-n-butyl-1kappaC%2C2kappaC%2C3kappaC%2C4kappaC-tetra-kis%28mu-2-hydroxy-benzoato%29-12_kappaOO%3B23kappaOO%27%3B34kappaOO%3B14kappaOO%27-di-mu%283%29-oxido-123kappaOOO%3B13_4kappaOOO-tetra-tin.pdf |
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| author | Reisi, Reza Shahirin, Siti Munirah Misran, Misni Lo, Kong Mun Ng, Seik Weng |
| author_facet | Reisi, Reza Shahirin, Siti Munirah Misran, Misni Lo, Kong Mun Ng, Seik Weng |
| author_sort | Reisi, Reza |
| collection | UM |
| description | In the centrosymmetric tetranuclear title compound, [Sn4(C4H9)8(C7H5O3)4O2], one of the two independent Sn atoms is five-coordinate in a cis-C2SnO3 trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) interaction [Sn⋯O = 2.862 (1) Å]. The other Sn atom has a bent R 2Sn skeleton [C—Sn—C = 144.0 (1)°], but the geometry is best regarded as being a trans-C2SnO4 octahedron as the Sn–O(single bond) interaction is shorter [Sn—O = 2.674 (1) Å]. |
| first_indexed | 2024-03-06T05:17:19Z |
| format | Article |
| id | um.eprints-6850 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:17:19Z |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-68502020-12-11T06:39:44Z http://eprints.um.edu.my/6850/ Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV) Reisi, Reza Shahirin, Siti Munirah Misran, Misni Lo, Kong Mun Ng, Seik Weng QD Chemistry In the centrosymmetric tetranuclear title compound, [Sn4(C4H9)8(C7H5O3)4O2], one of the two independent Sn atoms is five-coordinate in a cis-C2SnO3 trigonal-bipyramidal geometry [C—Sn—C = 142.7 (1)°]; the geometry is distorted owing to a long Sn⋯O(double bond) interaction [Sn⋯O = 2.862 (1) Å]. The other Sn atom has a bent R 2Sn skeleton [C—Sn—C = 144.0 (1)°], but the geometry is best regarded as being a trans-C2SnO4 octahedron as the Sn–O(single bond) interaction is shorter [Sn—O = 2.674 (1) Å]. International Union of Crystallography 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/6850/1/Octa-n-butyl-1kappaC%2C2kappaC%2C3kappaC%2C4kappaC-tetra-kis%28mu-2-hydroxy-benzoato%29-12_kappaOO%3B23kappaOO%27%3B34kappaOO%3B14kappaOO%27-di-mu%283%29-oxido-123kappaOOO%3B13_4kappaOOO-tetra-tin.pdf Reisi, Reza and Shahirin, Siti Munirah and Misran, Misni and Lo, Kong Mun and Ng, Seik Weng (2008) Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV). Acta Crystallographica Section E: Structure Reports Online, 64 (8). m1103. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536808023787 <https://doi.org/10.1107/S1600536808023787>. https://doi.org/10.1107/S1600536808023787 doi:10.1107/S1600536808023787 |
| spellingShingle | QD Chemistry Reisi, Reza Shahirin, Siti Munirah Misran, Misni Lo, Kong Mun Ng, Seik Weng Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV) |
| title | Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV) |
| title_full | Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV) |
| title_fullStr | Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV) |
| title_full_unstemmed | Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV) |
| title_short | Octa-n-butyl-1κ 2 C,2κ 2 C,3κ 2 C,4κ 2 C-tetrakis(μ-2-hydroxybenzoato)-1:2κ 2 O:O;2:3κ2 O:O′;3:4κ 2 O:O;1:4κ 2 O:O′-di-μ 3-oxido-1:2:3κ 3 O:O:O;1:3:4κ 3 O:O:O-tetratin(IV) |
| title_sort | octa n butyl 1κ 2 c 2κ 2 c 3κ 2 c 4κ 2 c tetra kis μ 2 hydroxy benzoato 1 2κ 2 o o 2 3κ2 o o 3 4κ 2 o o 1 4κ 2 o o di μ 3 oxido 1 2 3κ 3 o o o 1 3 4κ 3 o o o tetra tin iv |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/6850/1/Octa-n-butyl-1kappaC%2C2kappaC%2C3kappaC%2C4kappaC-tetra-kis%28mu-2-hydroxy-benzoato%29-12_kappaOO%3B23kappaOO%27%3B34kappaOO%3B14kappaOO%27-di-mu%283%29-oxido-123kappaOOO%3B13_4kappaOOO-tetra-tin.pdf |
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