(2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II)
The Zn-II atom in the title compound, [Zn(C8H7N3O2S)-(C10H8N2)], is N,N'-chelated by the heterocycle and N, O, S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O-H center dot center dot center dot O and N-H center dot center dot center dot N...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/6960/1/Tan-2009-%282%2C2_%27-Bipyridine-ka.pdf |
| _version_ | 1825719301172101120 |
|---|---|
| author | Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. |
| author_facet | Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. |
| author_sort | Tan, Kong Wai |
| collection | UM |
| description | The Zn-II atom in the title compound, [Zn(C8H7N3O2S)-(C10H8N2)], is N,N'-chelated by the heterocycle and N, O, S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O-H center dot center dot center dot O and N-H center dot center dot center dot N hydrogen bonds link adjacent molecules into a layer structure. |
| first_indexed | 2024-03-06T05:17:35Z |
| format | Article |
| id | um.eprints-6960 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:17:35Z |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-69602019-01-30T08:52:17Z http://eprints.um.edu.my/6960/ (2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II) Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. QD Chemistry The Zn-II atom in the title compound, [Zn(C8H7N3O2S)-(C10H8N2)], is N,N'-chelated by the heterocycle and N, O, S-chelated by the doubly deprotonated Schiff base ligand in a distorted square-pyramidal environment. O-H center dot center dot center dot O and N-H center dot center dot center dot N hydrogen bonds link adjacent molecules into a layer structure. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/6960/1/Tan-2009-%282%2C2_%27-Bipyridine-ka.pdf Tan, Kong Wai and Ng, S.W. and Maah, Mohd Jamil and Ng, C.H. (2009) (2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II). Acta Crystallographica Section E: Structure Reports Online, 65. M143-U303. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536808043973 <https://doi.org/10.1107/s1600536808043973>. http://journals.iucr.org/e/issues/2009/02/00/tk2348/tk2348.pdf 10.1107/s1600536808043973 |
| spellingShingle | QD Chemistry Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. (2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II) |
| title | (2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II) |
| title_full | (2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II) |
| title_fullStr | (2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II) |
| title_full_unstemmed | (2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II) |
| title_short | (2,2 '-Bipyridine-kappa N-2,N ')(4-hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)zinc(II) |
| title_sort | 2 2 bipyridine kappa n 2 n 4 hydroxy 2 oxidobenzaldehyde thiosemicarbazonato kappa o 3 2 n 1 s zinc ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/6960/1/Tan-2009-%282%2C2_%27-Bipyridine-ka.pdf |
| work_keys_str_mv | AT tankongwai 22bipyridinekappan2n4hydroxy2oxidobenzaldehydethiosemicarbazonatokappao32n1szincii AT ngsw 22bipyridinekappan2n4hydroxy2oxidobenzaldehydethiosemicarbazonatokappao32n1szincii AT maahmohdjamil 22bipyridinekappan2n4hydroxy2oxidobenzaldehydethiosemicarbazonatokappao32n1szincii AT ngch 22bipyridinekappan2n4hydroxy2oxidobenzaldehydethiosemicarbazonatokappao32n1szincii |