(1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1)
The ZnII atom in the title compound, [Zn(C14H 11N3O2S)(C12H8N 2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr-oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is locate...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2009
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Online Access: | http://eprints.um.edu.my/6962/1/Tan-2009-%281%2C10-phenanthroline.pdf |
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author | Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. |
author_facet | Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. |
author_sort | Tan, Kong Wai |
collection | UM |
description | The ZnII atom in the title compound, [Zn(C14H 11N3O2S)(C12H8N 2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr-oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supra-molecular trimeric unit. © 2009 Tan et al. |
first_indexed | 2024-03-06T05:17:35Z |
format | Article |
id | um.eprints-6962 |
institution | Universiti Malaya |
language | English |
last_indexed | 2024-03-06T05:17:35Z |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | dspace |
spelling | um.eprints-69622019-01-31T05:27:10Z http://eprints.um.edu.my/6962/ (1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1) Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. QD Chemistry The ZnII atom in the title compound, [Zn(C14H 11N3O2S)(C12H8N 2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr-oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supra-molecular trimeric unit. © 2009 Tan et al. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/6962/1/Tan-2009-%281%2C10-phenanthroline.pdf Tan, Kong Wai and Ng, S.W. and Maah, Mohd Jamil and Ng, C.H. (2009) (1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1). Acta Crystallographica Section E: Structure Reports Online, 65 (8). ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536809026245 <https://doi.org/10.1107/S1600536809026245>. http://journals.iucr.org/e/issues/2009/08/00/tk2484/tk2484.pdf 10.1107/S1600536809026245 |
spellingShingle | QD Chemistry Tan, Kong Wai Ng, S.W. Maah, Mohd Jamil Ng, C.H. (1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1) |
title | (1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1) |
title_full | (1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1) |
title_fullStr | (1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1) |
title_full_unstemmed | (1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1) |
title_short | (1,10-phenanthroline-2 N,N′)zinc(II)-4,4′-bipyridine (2/1) |
title_sort | 1 10 phenanthroline 2 n n zinc ii 4 4 bipyridine 2 1 |
topic | QD Chemistry |
url | http://eprints.um.edu.my/6962/1/Tan-2009-%281%2C10-phenanthroline.pdf |
work_keys_str_mv | AT tankongwai 110phenanthroline2nnzincii44bipyridine21 AT ngsw 110phenanthroline2nnzincii44bipyridine21 AT maahmohdjamil 110phenanthroline2nnzincii44bipyridine21 AT ngch 110phenanthroline2nnzincii44bipyridine21 |