Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon

Fixed-bed adsorption studies with virgin and polyethyleneimine (PEI)-impregnated palm shell activated carbon (AC) as a media for the removal of single Ni2+ or Cu2+ ions from aqueous solution were conducted. The studies were conducted in a vertical down flow Perspex column with influent pH at 5 with...

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Main Authors: Yin, C.Y., Aroua, M.K., Daud, W.M.A.W.
Format: Article
Published: Elsevier 2009
Subjects:
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author Yin, C.Y.
Aroua, M.K.
Daud, W.M.A.W.
author_facet Yin, C.Y.
Aroua, M.K.
Daud, W.M.A.W.
author_sort Yin, C.Y.
collection UM
description Fixed-bed adsorption studies with virgin and polyethyleneimine (PEI)-impregnated palm shell activated carbon (AC) as a media for the removal of single Ni2+ or Cu2+ ions from aqueous solution were conducted. The studies were conducted in a vertical down flow Perspex column with influent pH at 5 with either Ni2+ or Cu2+ had an influent concentration of 1 mmol/L. The adsorption data were fitted to three-well-established fixed-bed adsorption models, namely, bed-depth-service-time (BDST), Thomas and Yoon-Nelson models. It was observed that PEI impregnation at 8.41 wt had increased the breakthrough volume and service time of AC by factors of 2.1 (Cu2+) and 1.6 (Ni2+) as compared to virgin AC. For Cu2+ adsorption, the modelled BDST, Thomas and Yoon-Nelson curves were in very good agreement with the experimental curves while it was conversely true for Ni2+ adsorption. © 2008 Elsevier B.V. All rights reserved.
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spelling um.eprints-74372025-02-07T07:20:27Z http://eprints.um.edu.my/7437/ Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon Yin, C.Y. Aroua, M.K. Daud, W.M.A.W. TA Engineering (General). Civil engineering (General) TP Chemical technology Fixed-bed adsorption studies with virgin and polyethyleneimine (PEI)-impregnated palm shell activated carbon (AC) as a media for the removal of single Ni2+ or Cu2+ ions from aqueous solution were conducted. The studies were conducted in a vertical down flow Perspex column with influent pH at 5 with either Ni2+ or Cu2+ had an influent concentration of 1 mmol/L. The adsorption data were fitted to three-well-established fixed-bed adsorption models, namely, bed-depth-service-time (BDST), Thomas and Yoon-Nelson models. It was observed that PEI impregnation at 8.41 wt had increased the breakthrough volume and service time of AC by factors of 2.1 (Cu2+) and 1.6 (Ni2+) as compared to virgin AC. For Cu2+ adsorption, the modelled BDST, Thomas and Yoon-Nelson curves were in very good agreement with the experimental curves while it was conversely true for Ni2+ adsorption. © 2008 Elsevier B.V. All rights reserved. Elsevier 2009 Article PeerReviewed Yin, C.Y. and Aroua, M.K. and Daud, W.M.A.W. (2009) Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon. Chemical Engineering Journal, 148 (1). pp. 8-14. ISSN 1385-8947, DOI https://doi.org/10.1016/j.cej.2008.07.032 <https://doi.org/10.1016/j.cej.2008.07.032>. http://www.sciencedirect.com/science/article/pii/S1385894708004324 DOI 10.1016/j.cej.2008.07.032
spellingShingle TA Engineering (General). Civil engineering (General)
TP Chemical technology
Yin, C.Y.
Aroua, M.K.
Daud, W.M.A.W.
Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon
title Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon
title_full Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon
title_fullStr Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon
title_full_unstemmed Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon
title_short Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon
title_sort fixed bed adsorption of metal ions from aqueous solution on polyethyleneimine impregnated palm shell activated carbon
topic TA Engineering (General). Civil engineering (General)
TP Chemical technology
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