Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC)

In this work, a chitosan/iota (iota)-carrageenan blended film doped with orthophosphoric acid (H(3)PO(4)) as ionic dopant and poly(ethylene glycol) (PEG) as plasticizer has been used as a separator and electrolyte in an electrical double layer capacitor (EDLC). A set of samples were prepared by the...

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Main Authors: Kufian, M.Z., Majid, Siti Rohana, Arof, Abdul Kariem, Shuhaimi, N.E.A., Alias, N.A.
Format: Article
Published: Springer Verlag (Germany) 2010
Subjects:
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author Kufian, M.Z.
Majid, Siti Rohana
Arof, Abdul Kariem
Shuhaimi, N.E.A.
Alias, N.A.
author_facet Kufian, M.Z.
Majid, Siti Rohana
Arof, Abdul Kariem
Shuhaimi, N.E.A.
Alias, N.A.
author_sort Kufian, M.Z.
collection UM
description In this work, a chitosan/iota (iota)-carrageenan blended film doped with orthophosphoric acid (H(3)PO(4)) as ionic dopant and poly(ethylene glycol) (PEG) as plasticizer has been used as a separator and electrolyte in an electrical double layer capacitor (EDLC). A set of samples were prepared by the solution cast technique to see the effect of the different weight ratios of the proton donor and plasticizer on the conductivity. The highest conducting sample has composition 37.50 wt.% chitosan-37.50 wt.% iota-carrageenan-18.75 wt.% H(3)PO(4)-6.25 wt.% PEG. The conductivity value is 6.29 x 10(-4) S cm(-1). The conductivity-temperature relationship is Arrhenian, and the activation energy for the highest conducting sample is 0.09 eV. The specific discharge capacitance of the EDLC is 35 F g(-1) at 0.11 mA cm(-2) current drain and was constant for 30 cycles.
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spelling um.eprints-76492019-08-27T01:17:19Z http://eprints.um.edu.my/7649/ Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC) Kufian, M.Z. Majid, Siti Rohana Arof, Abdul Kariem Shuhaimi, N.E.A. Alias, N.A. QC Physics In this work, a chitosan/iota (iota)-carrageenan blended film doped with orthophosphoric acid (H(3)PO(4)) as ionic dopant and poly(ethylene glycol) (PEG) as plasticizer has been used as a separator and electrolyte in an electrical double layer capacitor (EDLC). A set of samples were prepared by the solution cast technique to see the effect of the different weight ratios of the proton donor and plasticizer on the conductivity. The highest conducting sample has composition 37.50 wt.% chitosan-37.50 wt.% iota-carrageenan-18.75 wt.% H(3)PO(4)-6.25 wt.% PEG. The conductivity value is 6.29 x 10(-4) S cm(-1). The conductivity-temperature relationship is Arrhenian, and the activation energy for the highest conducting sample is 0.09 eV. The specific discharge capacitance of the EDLC is 35 F g(-1) at 0.11 mA cm(-2) current drain and was constant for 30 cycles. Springer Verlag (Germany) 2010 Article PeerReviewed Kufian, M.Z. and Majid, Siti Rohana and Arof, Abdul Kariem and Shuhaimi, N.E.A. and Alias, N.A. (2010) Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC). Journal of Solid State Electrochemistry, 14 (12). pp. 2145-2152. ISSN 1432-8488, DOI https://doi.org/10.1007/s10008-010-1050-8 <https://doi.org/10.1007/s10008-010-1050-8>. https://doi.org/10.1007/s10008-010-1050-8 doi:10.1007/s10008-010-1050-8
spellingShingle QC Physics
Kufian, M.Z.
Majid, Siti Rohana
Arof, Abdul Kariem
Shuhaimi, N.E.A.
Alias, N.A.
Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC)
title Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC)
title_full Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC)
title_fullStr Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC)
title_full_unstemmed Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC)
title_short Application of chitosan/iota-carrageenan polymer electrolytes in electrical double layer capacitor (EDLC)
title_sort application of chitosan iota carrageenan polymer electrolytes in electrical double layer capacitor edlc
topic QC Physics
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