Plasticized chitosan-PVA blend polymer electrolyte based proton battery
This paper focused on the transport studies of PVA-chitosan blended electrolyte system and application in proton batteries. The electrolytes were prepared by the solution cast technique. In this work, 36 wt.% PVA and 24 wt.% chitosan blend doped with 40 wt.% NH(4)NO(3) exhibited the highest room tem...
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Elsevier
2010
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author | Majid, Siti Rohana Arof, Abdul Kariem Kadir, M.F.Z. |
author_facet | Majid, Siti Rohana Arof, Abdul Kariem Kadir, M.F.Z. |
author_sort | Majid, Siti Rohana |
collection | UM |
description | This paper focused on the transport studies of PVA-chitosan blended electrolyte system and application in proton batteries. The electrolytes were prepared by the solution cast technique. In this work, 36 wt.% PVA and 24 wt.% chitosan blend doped with 40 wt.% NH(4)NO(3) exhibited the highest room temperature conductivity. The conductivity value obtained was 2.07 x 10(-5) S cm(-1). EC was then added in various quantities to the 60 wt.% [60 wt.% PVA-40 wt.% chitosan]-40 wt.% NH(4)NO(3) composition in order to enhance the conductivity of the sample. The highest conductivity obtained was 1.60 x 10(-3) S cm(-1) for the sample containing 70 wt.% EC. The Rice and Roth model was applied to analyze the conductivity enhancement. The highest conducting sample in the plasticized system was used to fabricate several batteries with configuration Zn//MnO(2). The open circuit potential (OCP) of the fabricated batteries was between 1.6 and 1.7 V. (C) 2009 Elsevier Ltd. All rights reserved. |
first_indexed | 2024-03-06T05:19:13Z |
format | Article |
id | um.eprints-7653 |
institution | Universiti Malaya |
last_indexed | 2024-03-06T05:19:13Z |
publishDate | 2010 |
publisher | Elsevier |
record_format | dspace |
spelling | um.eprints-76532019-08-27T01:21:01Z http://eprints.um.edu.my/7653/ Plasticized chitosan-PVA blend polymer electrolyte based proton battery Majid, Siti Rohana Arof, Abdul Kariem Kadir, M.F.Z. QC Physics This paper focused on the transport studies of PVA-chitosan blended electrolyte system and application in proton batteries. The electrolytes were prepared by the solution cast technique. In this work, 36 wt.% PVA and 24 wt.% chitosan blend doped with 40 wt.% NH(4)NO(3) exhibited the highest room temperature conductivity. The conductivity value obtained was 2.07 x 10(-5) S cm(-1). EC was then added in various quantities to the 60 wt.% [60 wt.% PVA-40 wt.% chitosan]-40 wt.% NH(4)NO(3) composition in order to enhance the conductivity of the sample. The highest conductivity obtained was 1.60 x 10(-3) S cm(-1) for the sample containing 70 wt.% EC. The Rice and Roth model was applied to analyze the conductivity enhancement. The highest conducting sample in the plasticized system was used to fabricate several batteries with configuration Zn//MnO(2). The open circuit potential (OCP) of the fabricated batteries was between 1.6 and 1.7 V. (C) 2009 Elsevier Ltd. All rights reserved. Elsevier 2010 Article PeerReviewed Majid, Siti Rohana and Arof, Abdul Kariem and Kadir, M.F.Z. (2010) Plasticized chitosan-PVA blend polymer electrolyte based proton battery. Electrochimica Acta, 55 (4). pp. 1475-1482. ISSN 0013-4686, DOI https://doi.org/10.1016/j.electacta.2009.05.011 <https://doi.org/10.1016/j.electacta.2009.05.011>. https://doi.org/10.1016/j.electacta.2009.05.011 doi:10.1016/j.electacta.2009.05.011 |
spellingShingle | QC Physics Majid, Siti Rohana Arof, Abdul Kariem Kadir, M.F.Z. Plasticized chitosan-PVA blend polymer electrolyte based proton battery |
title | Plasticized chitosan-PVA blend polymer electrolyte based proton battery |
title_full | Plasticized chitosan-PVA blend polymer electrolyte based proton battery |
title_fullStr | Plasticized chitosan-PVA blend polymer electrolyte based proton battery |
title_full_unstemmed | Plasticized chitosan-PVA blend polymer electrolyte based proton battery |
title_short | Plasticized chitosan-PVA blend polymer electrolyte based proton battery |
title_sort | plasticized chitosan pva blend polymer electrolyte based proton battery |
topic | QC Physics |
work_keys_str_mv | AT majidsitirohana plasticizedchitosanpvablendpolymerelectrolytebasedprotonbattery AT arofabdulkariem plasticizedchitosanpvablendpolymerelectrolytebasedprotonbattery AT kadirmfz plasticizedchitosanpvablendpolymerelectrolytebasedprotonbattery |