Plasticized chitosan-PVA blend polymer electrolyte based proton battery

This paper focused on the transport studies of PVA-chitosan blended electrolyte system and application in proton batteries. The electrolytes were prepared by the solution cast technique. In this work, 36 wt.% PVA and 24 wt.% chitosan blend doped with 40 wt.% NH(4)NO(3) exhibited the highest room tem...

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Main Authors: Majid, Siti Rohana, Arof, Abdul Kariem, Kadir, M.F.Z.
Format: Article
Published: Elsevier 2010
Subjects:
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author Majid, Siti Rohana
Arof, Abdul Kariem
Kadir, M.F.Z.
author_facet Majid, Siti Rohana
Arof, Abdul Kariem
Kadir, M.F.Z.
author_sort Majid, Siti Rohana
collection UM
description This paper focused on the transport studies of PVA-chitosan blended electrolyte system and application in proton batteries. The electrolytes were prepared by the solution cast technique. In this work, 36 wt.% PVA and 24 wt.% chitosan blend doped with 40 wt.% NH(4)NO(3) exhibited the highest room temperature conductivity. The conductivity value obtained was 2.07 x 10(-5) S cm(-1). EC was then added in various quantities to the 60 wt.% [60 wt.% PVA-40 wt.% chitosan]-40 wt.% NH(4)NO(3) composition in order to enhance the conductivity of the sample. The highest conductivity obtained was 1.60 x 10(-3) S cm(-1) for the sample containing 70 wt.% EC. The Rice and Roth model was applied to analyze the conductivity enhancement. The highest conducting sample in the plasticized system was used to fabricate several batteries with configuration Zn//MnO(2). The open circuit potential (OCP) of the fabricated batteries was between 1.6 and 1.7 V. (C) 2009 Elsevier Ltd. All rights reserved.
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spelling um.eprints-76532019-08-27T01:21:01Z http://eprints.um.edu.my/7653/ Plasticized chitosan-PVA blend polymer electrolyte based proton battery Majid, Siti Rohana Arof, Abdul Kariem Kadir, M.F.Z. QC Physics This paper focused on the transport studies of PVA-chitosan blended electrolyte system and application in proton batteries. The electrolytes were prepared by the solution cast technique. In this work, 36 wt.% PVA and 24 wt.% chitosan blend doped with 40 wt.% NH(4)NO(3) exhibited the highest room temperature conductivity. The conductivity value obtained was 2.07 x 10(-5) S cm(-1). EC was then added in various quantities to the 60 wt.% [60 wt.% PVA-40 wt.% chitosan]-40 wt.% NH(4)NO(3) composition in order to enhance the conductivity of the sample. The highest conductivity obtained was 1.60 x 10(-3) S cm(-1) for the sample containing 70 wt.% EC. The Rice and Roth model was applied to analyze the conductivity enhancement. The highest conducting sample in the plasticized system was used to fabricate several batteries with configuration Zn//MnO(2). The open circuit potential (OCP) of the fabricated batteries was between 1.6 and 1.7 V. (C) 2009 Elsevier Ltd. All rights reserved. Elsevier 2010 Article PeerReviewed Majid, Siti Rohana and Arof, Abdul Kariem and Kadir, M.F.Z. (2010) Plasticized chitosan-PVA blend polymer electrolyte based proton battery. Electrochimica Acta, 55 (4). pp. 1475-1482. ISSN 0013-4686, DOI https://doi.org/10.1016/j.electacta.2009.05.011 <https://doi.org/10.1016/j.electacta.2009.05.011>. https://doi.org/10.1016/j.electacta.2009.05.011 doi:10.1016/j.electacta.2009.05.011
spellingShingle QC Physics
Majid, Siti Rohana
Arof, Abdul Kariem
Kadir, M.F.Z.
Plasticized chitosan-PVA blend polymer electrolyte based proton battery
title Plasticized chitosan-PVA blend polymer electrolyte based proton battery
title_full Plasticized chitosan-PVA blend polymer electrolyte based proton battery
title_fullStr Plasticized chitosan-PVA blend polymer electrolyte based proton battery
title_full_unstemmed Plasticized chitosan-PVA blend polymer electrolyte based proton battery
title_short Plasticized chitosan-PVA blend polymer electrolyte based proton battery
title_sort plasticized chitosan pva blend polymer electrolyte based proton battery
topic QC Physics
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AT arofabdulkariem plasticizedchitosanpvablendpolymerelectrolytebasedprotonbattery
AT kadirmfz plasticizedchitosanpvablendpolymerelectrolytebasedprotonbattery