A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol
In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 angstrom) is coplanar with the phenylene ring (r.m.s. deviation = 0.007 angstrom), the two rings being slightly bent at 2.6 (1)degrees. The hydroxy H ato...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/8021/1/Asiri-2010-A_monoclinic_modific.pdf |
| _version_ | 1825719470840086528 |
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| author | Tan, Kong Wai Ng, S.W. Asiri, A.M. Khan, S.A. |
| author_facet | Tan, Kong Wai Ng, S.W. Asiri, A.M. Khan, S.A. |
| author_sort | Tan, Kong Wai |
| collection | UM |
| description | In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 angstrom) is coplanar with the phenylene ring (r.m.s. deviation = 0.007 angstrom), the two rings being slightly bent at 2.6 (1)degrees. The hydroxy H atom forms an intramolecular hydrogen bond to the imino group. The bond dimensions of the monoclinic modification are similar to those of the orthorhombic modification [Liu et al. (2009). Acta Cryst. E65, o738]. |
| first_indexed | 2024-03-06T05:20:14Z |
| format | Article |
| id | um.eprints-8021 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:20:14Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-80212019-01-30T08:51:28Z http://eprints.um.edu.my/8021/ A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol Tan, Kong Wai Ng, S.W. Asiri, A.M. Khan, S.A. QD Chemistry In the title Schiff base, C(14)H(10)N(2)OS, the azomethine double bond is in an E configuration; the benzothiazolyl ring (r.m.s. deviation = 0.007 angstrom) is coplanar with the phenylene ring (r.m.s. deviation = 0.007 angstrom), the two rings being slightly bent at 2.6 (1)degrees. The hydroxy H atom forms an intramolecular hydrogen bond to the imino group. The bond dimensions of the monoclinic modification are similar to those of the orthorhombic modification [Liu et al. (2009). Acta Cryst. E65, o738]. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/8021/1/Asiri-2010-A_monoclinic_modific.pdf Tan, Kong Wai and Ng, S.W. and Asiri, A.M. and Khan, S.A. (2010) A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol. Acta Crystallographica Section E: Structure Reports Online, 66 (7). O1826-U789. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810023755 <https://doi.org/10.1107/s1600536810023755>. http://journals.iucr.org/e/issues/2010/07/00/nk2043/nk2043.pdf 10.1107/s1600536810023755 |
| spellingShingle | QD Chemistry Tan, Kong Wai Ng, S.W. Asiri, A.M. Khan, S.A. A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol |
| title | A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol |
| title_full | A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol |
| title_fullStr | A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol |
| title_full_unstemmed | A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol |
| title_short | A monoclinic modification of 2-[(1,3benzothiazol-2-yl)iminomethyl]phenol |
| title_sort | monoclinic modification of 2 1 3benzothiazol 2 yl iminomethyl phenol |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/8021/1/Asiri-2010-A_monoclinic_modific.pdf |
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