(E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate
In the title molecule, C(10)H(13)N(3)O(3)S center dot 2H(2)O, the thiosemicarbazide =N-NH-C(=S)-NH- fragment [torsion angle = 0.2 (1)degrees] is nearly coplanar with the benzene ring [dihedral angle = 2.4 (1)degrees]. The benzene ring and semicarbazide moiety are located on opposite sites of the C=N...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/8028/1/Shawish-2010-%28E%29-1-%282%2C4%2C6-Trihydr.pdf |
| _version_ | 1825719472201138176 |
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| author | Tan, K.W. Ng, S.W. Shawish, H.B. Maah, Mohd Jamil |
| author_facet | Tan, K.W. Ng, S.W. Shawish, H.B. Maah, Mohd Jamil |
| author_sort | Tan, K.W. |
| collection | UM |
| description | In the title molecule, C(10)H(13)N(3)O(3)S center dot 2H(2)O, the thiosemicarbazide =N-NH-C(=S)-NH- fragment [torsion angle = 0.2 (1)degrees] is nearly coplanar with the benzene ring [dihedral angle = 2.4 (1)degrees]. The benzene ring and semicarbazide moiety are located on opposite sites of the C=N bond, showing an E configuration. The hydroxy, imino and water H atoms are engaged in extensive hydrogen bonding, forming a three-dimensional network. |
| first_indexed | 2024-03-06T05:20:16Z |
| format | Article |
| id | um.eprints-8028 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:20:16Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-80282019-01-30T08:34:36Z http://eprints.um.edu.my/8028/ (E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate Tan, K.W. Ng, S.W. Shawish, H.B. Maah, Mohd Jamil QD Chemistry In the title molecule, C(10)H(13)N(3)O(3)S center dot 2H(2)O, the thiosemicarbazide =N-NH-C(=S)-NH- fragment [torsion angle = 0.2 (1)degrees] is nearly coplanar with the benzene ring [dihedral angle = 2.4 (1)degrees]. The benzene ring and semicarbazide moiety are located on opposite sites of the C=N bond, showing an E configuration. The hydroxy, imino and water H atoms are engaged in extensive hydrogen bonding, forming a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/8028/1/Shawish-2010-%28E%29-1-%282%2C4%2C6-Trihydr.pdf Tan, K.W. and Ng, S.W. and Shawish, H.B. and Maah, Mohd Jamil (2010) (E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate. Acta Crystallographica Section E: Structure Reports Online, 66. O2230-U1613. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810030783 <https://doi.org/10.1107/s1600536810030783>. http://journals.iucr.org/e/issues/2010/09/00/xu5011/xu5011.pdf 10.1107/s1600536810030783 |
| spellingShingle | QD Chemistry Tan, K.W. Ng, S.W. Shawish, H.B. Maah, Mohd Jamil (E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate |
| title | (E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate |
| title_full | (E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate |
| title_fullStr | (E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate |
| title_full_unstemmed | (E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate |
| title_short | (E)-1-(2,4,6-Trihydroxybenzylidene)-4-ethylthiosemicarbazide dihydrate |
| title_sort | e 1 2 4 6 trihydroxybenzylidene 4 ethylthiosemicarbazide dihydrate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/8028/1/Shawish-2010-%28E%29-1-%282%2C4%2C6-Trihydr.pdf |
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